1979
Über den Einfluß von Wasser auf die Polymerisation von Hexachlorcyclotriphosphazen
Abstract: Herrn Professor Dr. Dr. h. c . Hermann Klare zur Vollendung des 70. Lebensjahres gewidrnetEs wurde gezeigt, dal3 die Anwesenheit von restlichem Wasser irn Reaktionssystem zur Hydrolyse der P-CI-Bindungen von Blockpolymerisaten von Hexachlorcyclotriphosphazen fuhrt. Auf Grund der Abschatzung des sich bei der Hydrolyse entwickelnden HCl und der IR-Spektren der Urnwandlungsprodukte auf verschiedenen Polymerisationsstufen wurde ein Schema der Hexachlorcyclotriphosphazenpolymerisation mit HCI vorgeschlagen. 0 saumm…
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“…Poly(dialkoxyphosphazenes) (−[NP(OR) 2 −] n −) with alkoxy substituents OR = OC 3 H 7 , OC 4 H 9 , OC 5 H 11 (designated as PDAP-C3, PDAP-C4, and PDAPC5, respectively), were prepared and kindly provided by Dr. Dzidra Tur. Their synthesis was described in detail earlier; − the digest is provided in the Supporting Information.…”
Section: Methodsmentioning
confidence: 99%
“…Poly(dialkoxyphosphazenes) (−[NP(OR) 2 −] n −) with alkoxy substituents OR = OC 3 H 7 , OC 4 H 9 , OC 5 H 11 (designated as PDAP-C3, PDAP-C4, and PDAPC5, respectively), were prepared and kindly provided by Dr. Dzidra Tur. Their synthesis was described in detail earlier; − the digest is provided in the Supporting Information.…”
Section: Methodsmentioning
confidence: 99%
“…Figure10. log (creep compliance), (JA) (cm2/dyn) vs. temperature (°C) for heating and cooling of samples 1 and 2. …”
mentioning
confidence: 99%
