Two New Thiophosphates with Interlocked Structures: AgTi2(PS4)3 and Ag2NbTi3P6S25

Angenault, J.; Cieren, X.; Wallez, Gilles; Quarton, M.

doi:10.1006/jssc.2000.8739

Cited by 28 publications

(25 citation statements)

References 31 publications

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“…The short distance is typical of Nb 4+ -Nb 4+ bonds 13 and the long Nb1-Nb2 distance shows that there is no significant intermetallic bonding interaction and such an arrangement is consistent with the highly resistive nature of the compound.…”

Section: Resultssupporting

confidence: 52%

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

2005

Bulletin of the Korean Chemical Society

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Section: Resultssupporting

confidence: 52%

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

2005

Bulletin of the Korean Chemical Society

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“…Bonding mode I has not been observed for chalcogenophosphates so far, but thiophosphates such as AgZnPS 4 [56] contain entities with fragment II. Bonding mode III is typically encountered in early transition metal compounds such as AgTi 2 (PS 4 ) 3 , [57] ATi 2 (PS 4 ) 3 , [58] and K 3 Ti 2 P 5 S 18 [59] 3-anion chains, whereas mode IV is found in K 3 Bi(PS 4 ) 2 .…”

Section: Bonding Of the Thiophosphate Connecting Groupsmentioning

confidence: 98%

“…In conjunction with the various possible coordination modes (see Scheme 2) of the polydentate ligands this leads to a complex and fascinating structural chemistry of the metal chalcogenide family. [56][57][58][59][60][61][62] In order to make it easier to classify and describe the relevant chalcogenide structures, let us examine the coordination modes of the three simplest thiophosphate ligands, PS 4 3-, P 2 S 6 4-, and P 2 S 7 4-. The bonding mode of a thiophosphate (and any other chalcogenometallate) group can be organized according to the number of sulfur atoms connected to metal atoms, i.e.…”

Section: Bonding Of the Thiophosphate Connecting Groupsmentioning

confidence: 99%

Comprehensive Uranium Thiophosphate Chemistry: Framework Compounds Based on Pseudotetrahedrally Coordinated Central Metal Atoms

Neuhausen

Hatscher

Panthöfer

et al. 2013

Zeitschrift anorg allge chemie

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Abstract. The new ternary compounds UP 2 S 6 , UP 2 S 7 , U(P 2 S 6 ) 2 , and U 3 (PS 4 ) 4 were prepared from uranium metal, phosphorus pentasulfide, and sulfur at 700°C. The crystal structures were determined by singlecrystal X-ray diffraction methods. UP 2 S 6 (I) crystallizes in the ZrP 2 S 6 structure type [tetragonal, P4 2 /m, a = 6.8058(7) Å, c = 9.7597(14) Å, Z = 2], which consists of central uranium(IV) atoms coordinated by P 2 S 6 4-anions (staggered conformation). The anions are two-dimensional connectors for four uranium cations arranged in one plane. The structure of UP 2 S 7 (II) [orthorhombic, Fddd, a = 8.9966 (15) ligands, the resulting 3D network contains large pores (diameter approx. 3.5 ϫ 16.7 Å). In the previously reported compound U(P 2 S 6 ) 2 (III) [I4 1 /a, a = 12.8776(9) Å, c = 9.8367(10) Å, Z = 2], the

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“…The P-S distances are in good agreement with the P-S bonding distances found in other thiophosphates. [9][10][11][12][13] Atoms S7 and S16 are terminal atoms and this is responsible for the short distances (P1-S7 1.973(6) Å; P2-S16 1.971(6) Å) and their large displacement parameters.…”

mentioning

confidence: 99%

Synthesis and Crystal Structure of a New One-dimensional Quaternary Thiophosphate, CsNb₂PS₁₀

Kwak¹,

Kim²,

Yun

et al. 2007

Bulletin of the Korean Chemical Society

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Group 5 transition metal thiophosphates form an interesting class of materials due to their low-dimensional structural varieties and interesting anisotropic properties.1 Especially, these low-dimensional compounds have been extensively investigated for potential applications as cathode materials of high energy density secondary batteries.2 Preparation of the alkali metal thiophosphates is crucial to understand the nature of the intercalation and to analyze their behavior during charge and discharge processes. This gives us motivation to insert alkali metals into the thiophosphates. However, no stable alkali metal intercalated product in this system has been obtained and structurally characterized. We believe that the crystallinity of the host structure is not maintained during the electrochemical insertion procedure. During the past decade we have applied halide flux method to bypass this problem. This technique exploits metal halides as a flux and as a reactant. The resultant products usually include various monovalent cations and this technique enabled us to find the first niobium thiophosphates containing alkali metals, KNb2PS10.3 During an effort to expand the range of compounds within the quaternary alkali metalgroup 5 metal-P-S system by substituting alkali metals, we were able to prepare single crystals of CsNb2PS10. Here we report the synthesis and characterization of a new quaternary thiophosphate, CsNb 2 PS 10 .The structure of CsNb 2 PS 10 is closely related to those of the previously reported group 5 metal thiophosphates,

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Two New Thiophosphates with Interlocked Structures: AgTi2(PS4)3 and Ag2NbTi3P6S25

Cited by 28 publications

References 31 publications

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Comprehensive Uranium Thiophosphate Chemistry: Framework Compounds Based on Pseudotetrahedrally Coordinated Central Metal Atoms

Synthesis and Crystal Structure of a New One-dimensional Quaternary Thiophosphate, CsNb₂PS₁₀

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Two New Thiophosphates with Interlocked Structures: AgTi2(PS4)3 and Ag2NbTi3P6S25

Cited by 28 publications

References 31 publications

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K0.5Ag0.5Nb2PS10

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K0.5Ag0.5Nb2PS10

Comprehensive Uranium Thiophosphate Chemistry: Framework Compounds Based on Pseudotetrahedrally Coordinated Central Metal Atoms

Synthesis and Crystal Structure of a New One-dimensional Quaternary Thiophosphate, CsNb2PS10

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Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Synthesis and Crystal Structure of a New One-dimensional Quaternary Thiophosphate, CsNb₂PS₁₀