Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K0.5Ag0.5Nb2PS10

doi:10.5012/bkcs.2005.26.2.309

Bulletin of the Korean Chemical Society

2005

DOI: 10.5012/bkcs.2005.26.2.309

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Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Abstract: Single crystals of the new pentanary thiophosphate, K0.5Ag0.5Nb2PS10 has been prepared through reactions of the elements with halide fluxes. The structure of K0.5Ag0.5Nb2PS10 has been analyzed by single crystal X-ray diffraction technique. The structure of K0.5Ag0.5Nb2PS10 is made up of one-dimensional ∞

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Cited by 11 publications

References 12 publications

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The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃

Schoop

Eger

Nuß

et al. 2017

Zeitschrift anorg allge chemie

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Abstract. We report the first examples of quinary rare earth thiophosphates with a fully ordered cation and anion distribution, Cs 5 Ln 3 X 3 (P 2 S 6 ) 2 (PS 4 ), (Ln = La, Ce and X = Br, Cl) as well as the quasi-quaternary Cs 10 Y 4 Cl 10 (P 2 S 6 ) 3 . These four new compounds crystallize in three different, unknown structure types. The yellowish, transparent, brittle Cs 5 Ce 3 Br 3 (P 2 S 6 ) 2 (PS 4 ) crystallizes in the orthorhombic space group Pnma (no. 62) with a = 13.276(3), b = 14.891(3), c = 19.593(4) Å, and V = 3873(1) Å 3 in a novel structure type. Colorless crystals of Cs 5 La 3 Br 3 (P 2 S 6 ) 2 (PS 4 ) and Cs 5 La 3 Cl 3 (P 2 S 6 ) 2 (PS 4 ) are isotypic and were obtained in the monoclinic space group P2 1 /m (no. 11) with a = 9.715(2), b = 14.310(3), c = 13.685(3) Å, β = 100.16(3)°a nd V = 1873(1) Å 3 and a = 9.513(2), b = 14.182(3), c = 13.699(3) Å,

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The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃

Schoop

Eger

Nuß

et al. 2017

Zeitschrift anorg allge chemie

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Syntheses, crystal structures and spectroscopic properties of Ag2Nb[P2S6][S2] and KAg2[PS4]

Bensch

2009

Journal of Solid State Chemistry

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AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap

Tang,

Xing,

Tang

et al. 2023

Journal of Solid State Chemistry

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Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

Cited by 11 publications

References 12 publications

The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃

The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃

Syntheses, crystal structures and spectroscopic properties of Ag2Nb[P2S6][S2] and KAg2[PS4]

AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap

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Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K0.5Ag0.5Nb2PS10

Cited by 11 publications

References 12 publications

The First Quinary Rare Earth Thiophosphates: Cs5Ln3X3(P2S6)2(PS4) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs10Y4Cl10(P2S6)3

The First Quinary Rare Earth Thiophosphates: Cs5Ln3X3(P2S6)2(PS4) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs10Y4Cl10(P2S6)3

Syntheses, crystal structures and spectroscopic properties of Ag2Nb[P2S6][S2] and KAg2[PS4]

AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap

Contact Info

Product

Resources

About

Synthesis and Crystal Structure of a New Pentanary Thiophosphate, K_0.5Ag_0.5Nb₂PS₁₀

The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃

The First Quinary Rare Earth Thiophosphates: Cs₅Ln₃X₃(P₂S₆)₂(PS₄) (Ln = La, Ce, X = Br, Cl) and the Quasi‐Quaternary Cs₁₀Y₄Cl₁₀(P₂S₆)₃