Two formate-bridging coordination polymers containing dinuclear zinc(II) macrocyclic components

Crystal structure and fluorescence/phosphorescence of two novel Cd(II) coordination polymers

“…Due to the diversity of their coordination geometry and coordination number, the metal ions with d 10 electron configuration can coordinate to versatile organic or inorganic ligands containing O, N, S or P donors, leading to a variety of complexes or coordination polymers. Such complexes usually exhibit unique structural features and functional properties, thus they can have wide potential applications [7][8][9][10]. These luminescent properties have been applied at different degree in the following area: medical treatment, diagnostics, biology, analytical separation and luminescent materials [11][12][13][14][15].…”

Synthesis and characterisation of double-layered octahedral coordination polymers built up from divalent metal ions, mixed carboxylate anions, and ethyl carbazate ligands

“…A large number of different carboxylates in combination with various neutral blocking ligands have been hitherto used to synthesis MOFs with different topologies [9][10][11]. As well as long-chain and aromatic carboxylates, simple anions such as formate and acetate are effective in forming MOFs, where their small size, strong coordinating power and flexible coordination modes lead to distinct structures, which are often layered [12][13][14][15][16].…”

Two novel compartmental macrocyclic dinuclear copper(II) complexes with μ2-Cl and μ2-OAc bridges

“…In our systematic work, a variety of chiral and achiral metallomacrocyclic complexes have been synthesized by sodium(I) template condensation [21][22][23][24][25][26][27][28] [29,30]. In this paper, we present two novel compartmental macrocyclic dinuclear copper(II) complexes, formulated as ½Cu II 2 ðLÞðl 2 -ClÞ Á 1:5ðH 2 OÞ (1) and ½Cu II 2 ðLÞðl 2 -OAcÞ Á ðDMFÞ (2), where LH 3 is a pentadentate ligand obtained from the Schiff base condensation between 3,5-di-tertbutyl-2-hydroxybenzaldehyde and 2,6-bis(aminomethyl)-4-chlorophenol in a molar ratio of 2:1.…”