2006
DOI: 10.1021/nl061287m
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Tunable Light Emission from Quantum-Confined Excitons in TiSi2-Catalyzed Silicon Nanowires

Abstract: Visible and near-infrared photoluminescence (PL) at room temperature is reported from Si nanowires (NWs) grown by chemical vapor deposition from TiSi2 catalyst sites. NWs grown with average diameter of 20 nm were etched and oxidized to thin and passivate the wires. The PL emission blue shifted continuously with decreasing nanowire diameter. Slowed oxidation was observed for small nanowire diameters and provides a high degree of control over the emission wavelength. Transmission electron microscopy, PL, and tim… Show more

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Cited by 108 publications
(81 citation statements)
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“…7,18 While bulk Si has an indirect band gap, 19 Si NWs usually have a direct band gap, which enables usage as optically active materials for photonics applications. 20,21 Since the current-voltage (I -V ) characteristics are important in circuits design, the transport properties of Si NWs have been widely reported within both theoretical and experimental frameworks. For a system that uses Li electrodes to connect the NW, applying the nonequilibrium Green's function method, the I -V characteristics have been studied as function of the NW geometry 17,22 and surface modifications created by atomic substitutions and vacancies.…”
Section: Introductionmentioning
confidence: 99%
“…7,18 While bulk Si has an indirect band gap, 19 Si NWs usually have a direct band gap, which enables usage as optically active materials for photonics applications. 20,21 Since the current-voltage (I -V ) characteristics are important in circuits design, the transport properties of Si NWs have been widely reported within both theoretical and experimental frameworks. For a system that uses Li electrodes to connect the NW, applying the nonequilibrium Green's function method, the I -V characteristics have been studied as function of the NW geometry 17,22 and surface modifications created by atomic substitutions and vacancies.…”
Section: Introductionmentioning
confidence: 99%
“…Semiconductor nanowires are of high interest as potential building blocks for future optical and electronic devices, such as high mobility transistors, bright LEDs and solar cells [1][2][3][4][5]. Avoiding the use of external catalysts such as gold as a seed for nucleation and growth of the nanowires has been and is a crucial issue.…”
Section: Introductionmentioning
confidence: 99%
“…Designing, etching, and manipulating silicon nanowires has become increasingly important to a variety of research areas including nanoelectromechanical systems, optics/plasmonics, 1 and nanoscale circuit elements. Specific applications include high surface area chemical sensors, 2 mechanical oscillators, 3,4 and piezoresistive sensors.…”
Section: Introductionmentioning
confidence: 99%