Tris‐ and Tetrakis(Triphenyl‐Phosphine)Platinum (0)

Synthesis of Tellurido‐Bridged IrPt2, IrPd2, and IrPtPd Clusters by Inserting Zero‐Valent Pt and Pd Centers into TeC Bonds

“…Complexes [Cp*Ir(CO) 2 ], [15] [Pt(PPh 3 ) 3 ], [16] [Pd(PPh 3 ) 4 ], [17] and TolTeTeTol [18] were prepared by reported methods. 195 Pt satellites, J P-P = 5 Hz, J Pt-P = 3790 Hz), 7.4 ppm (d with 195 Pt satellites, J P-P = 5 Hz, J Pt-P = 3700 Hz); elemental analysis (%) calcd for C 62.…”

Synthesis of Tellurido‐Bridged IrPt2, IrPd2, and IrPtPd Clusters by Inserting Zero‐Valent Pt and Pd Centers into TeC Bonds

“…Complexes [Cp*Ir(CO) 2 ], [15] [Pt(PPh 3 ) 3 ], [16] [Pd(PPh 3 ) 4 ], [17] and TolTeTeTol [18] were prepared by reported methods. Complexes [Cp*Ir(CO) 2 ], [15] [Pt(PPh 3 ) 3 ], [16] [Pd(PPh 3 ) 4 ], [17] and TolTeTeTol [18] were prepared by reported methods.…”

Preparation of palladium loaded carbon nanotubes and activated carbons for hydrogen sorption

“…Two different Pd (0) compounds have been probed, both of them soluble in toluene: Pd 2 (dba) 3 ·CHCl 3 [Tris-(dibenzylidene acetone) dipalladium (0)] and Pd(PPh 3 ) 4 [Tetrakis-triphenylphosphine palladium (0)] [10,11]. In the nanoparticle loading process, the carbon substrate and the Pd salt have been first added to distilled toluene and stirred until the solution has changed from reddish to yellow.…”