Tris(1H-benzimidazole-κN3)(thiodiacetato-κ3O,S,O′)cadmium(II) dihydrate

The synthesis, crystal structures, and luminescence of two lanthanide polynuclear complexes with the general formula [Ln2(tda)3(H2O)5]·3H2O (Ln = Sm, Eu; tda = thiodiacetato anion) are reported. The compounds were obtained by direct reaction of H2tda and lanthanide(III) chloride in an aqueous solution. The choice of the conditions of synthesis was based on speciation studies. The structure of the polymeric complexes contains Ln(III) ions in a tricapped trigonal prism geometry. The versatility of this ligand provides different coordination modes and provokes the formation of thick 2D sheets. Direct excitation of the Ln(III) ions gives place to the characteristic intra-configuration sharp luminescence emission of both complexes in the solid state.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Tris(1H-benzimidazole-κN³)(thiodiacetato-κ³O,S,O′)cadmium(II) dihydrate

Abstract: Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.011 Å R factor = 0.067 wR factor = 0.167 Data-to-parameter ratio = 13.8For details of how these key indicators were automatically derived from the article, see

Cited by 2 publications

References 6 publications

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

Lanthanide(III) Complexes with Thiodiacetato Ligand: Chemical Speciation, Synthesis, Crystal Structure, and Solid-State Luminescence

Contact Info

Product

Resources

About