Trihalomethanes minimization in drinking water by coagulation/flocculation/sedimentation with natural coagulant Moringa oleifera Lam and activated carbon filtration

Abstract

Water treatment plants are designed to remove turbidity and apparent colour, and produce safe water from a microbiological and chemical point of view. Disinfection is the step responsible for the microbiological security, for which chlorine is the most widely‐used agent, since it can react with organic matter present in raw water to form total trihalomethanes (TTHM), which are harmful to humans. In this context, it is proposed to evaluate the effectiveness of the combined process of coagulation, flocculation, and sedimentation (C/F/S) followed by an activated carbon column. The water for the tests was from the Pirapó River (Brazil) with low colour and turbidity. In C/F/S tests, natural coagulant solutions from Moringa oleifera (MO) degreased with ethanol (MO(et)) and hexane (MO(hex)) were compared to coagulant aluminum polychloride (PAC) with further filtration in an activated carbon column. For all these tests, removal efficiency of apparent colour, turbidity, dissolved organic carbon (DOC), and compounds with UV254nm absorption (UV254nm) were evaluated. The disinfection process was performed and residual chlorine and TTHM formation were evaluated. It was observed that the process of C/F/S using MO(et) followed by filtration through activated carbon was able to reduce the values ​​of physicochemical parameters (96 % removal for turbidity and apparent colour, 93 % for UV254nm, and 99 % for DOC) with reduced formation of TTHM (25.31 μg/L). Moreover, oil extraction with ethanol presents advantages over hexane due to being a solvent with good operational security, low toxicity, and being a bio‐renewable source, all characteristics not present in hexane.

Moringa oleifera leaf as a natural water purifier and causes decontamination of fecal-coliform bacteria

“…It was reported that tannins and polyphenols in M. oleifera have antibacterial properties (Khosravi and Behzadi, 2006;Manguro and Lemmen, 2007). In addition, in the previous works conducted by Ghebremichael, (2007); Santos et al, (2016), the coagulant proteins in MOL extracts diminished the count of E. coli. Williams et al, (2017) study confirmed that there were cationic polypeptide compounds in the MOL extracts that inhibited the fecal bacteria.…”

“…According to several previous studies, the active components of MOL that are responsible for pH reduction in the treated water samples are the watersoluble and thermo-resistant proteins, and the free fatty acids that exist in the Moringa powders (Baptista et al, 2017;Semanka et al, 2022). In addition, Santos et al, (2016); Nordmark et al, (2018) previously proposed that MOL proteins have a considerable adsorption affinity for destabilizing the particulate dispersions, which lowers the pH level.…”