Triethyl ammonium salt of O,O′-bis(p-tolyl)dithiophosphate, [Et3NH]+[(4-MeC6H4O)2PS2]−

Synthesis and spectroscopic characterization of dimethyl/di(n‐butyl)tin(IV)bis(O,O′‐ditolyl dithiophosphate) complexes. Crystal structures of Me2Sn[S2P(OC6H4Me‐o)2]2 and n‐Bu2Sn[S2P(OC6H4Me‐o)2]2

“…• for S(1)-Sn(1)-C(1) in 1 and 4 to 109.85 (7) • and 108.19(7) 24,25 Ammonium salts of the dithiophosphoric acids were prepared by reaction of parent acid with ammonia in benzene.…”

Synthesis and spectroscopic characterization of toluene-3,4-dithiolatoarsenic(III)-O,O’-ditolyl/alkylene dithiophosphate compounds: crystal structure of [CH3C6H3S2As{S2P(OC6H4Me-m)2}]

“…SOCl 2 , o-, m-, p-cresols, and solvents (benzene, n-hexane) (E. Merck) were distilled prior to use. Literature methods were used for the preparation of O,O'-ditolyl [22][23][24] and alkylene dithiophosphoric acids [25]. Ammonium salts of the dithiophosphoric acids were prepared by reaction of the parent acid with an equimolar amount of ammonia in benzene.…”

“…IR spectra (table 2) of the toluene-3,4-dithiolatoarsenic(III) ditolyl/alkylene dithiophosphate complexes have been measured from 350 to 4000 cm −1 and the important bands have been assigned on the basis of comparison with spectra of salts of O,O'-di(o-, m-or p-tolyl) [23,24] and alkylene dithiophosphoric acids [25] and analogous compounds [33].…”

Synthesis and Spectroscopic Characterization of Mononuclear Oxomolybdenum(IV)O,O′-Ditolyl Dithiophosphate Complexes and Their Adducts With 2,2′-Bipyridyl and 1,10-Phenanthroline

“…Literature methods were used for the preparation of the ammonium salt of O,O 0 -ditolyl dithiophosphoric acids. [20,21] Synthesis of MoO[S 2 P(OC 6 …”

“…The assignments of the IR bands for oxomolybdenum(IV)O, O'-ditolyl dithiophosphate complexes (Table 1) were made by comparison with the spectra of the precursors complexes, the ammonium salts of O,O'-ditolyl dithiophosphates [20,21] and oxomolybdenum(IV) dialkyl dithiophosphates. [22] The bands due to y(P)-O-C and y P-O-(C), which occur in the regions 1139-1102 and 833-792 cm ¡1 , respectively, in the parent ammonium salts, do not show much change in the oxomolybdenum(IV) complexes.…”