Abstract:N‐Diazonium ions like (2) generally react in the same way as C‐diazonium ions by elimination of N2. The reaction of 2‐tetrazenium salts (1) with anionic nucleophiles Z⊖ shown below is new: the N3 sequence of (2) is retained in the products (3), formally the result of coupling between (2) and Z⊖.
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