Transition metal N,N-diethyldiselenocarbamates

How a Transition‐Metal(II) Chloride Interacts with a Eutectic AlCl3‐Based Ionic Liquid: Insights into the Speciation of the Electrolyte and Electrodeposition of Magnetic Materials

“…The salts consisting of [FeCl 4 ] 2− anions do not absorb in the visible region, but have an absorption band around 4000 cm −1 . In the electronic spectra, quite clear peaks were observed for FeCl 2 /[Py 1,4 ][TfO] and for (FeCl 2 +AlCl 3 )/[Py 1,4 ][TfO] at 242, 313, and 363 nm, respectively.…”

Studies of the thermal decomposition of some diselenocarbamato complexes of cadmium or zinc: molecular design for the deposition of MSe films by CVD

“…M(Se 2 CNEt 2 ) 2 , M~Zn 1 or Cd 2. Compounds 1 and 2 were prepared by a slight modi®cation of the methods of Barnard and Woodbridge 17 and Fulrani et al 18 The CSe 2 was used immediately after preparation and allowed to react with an excess of diethylamine in pentane at 0 ³C to give diethyldiselenocarbamate as the diethyl ammonium salt. 19 The selenocarbamate was then allowed to react with a stoichiometric quantity of an aqueous solution of zinc sulfate to give an insoluble yellow precipitate of compound 1 Zn(Se 2 CNEt 2 ) 2 .…”

Multidentate ligand kinetics. XIV. Formation and dissociation kinetics of rare earth-cyclohexylenediaminetetraacetate complexes

“…However, the structure of the multidentate ligand can greatly alter the rate from that predicted if several coordination steps must occur simultaneously as is the case in some macrocyclic structures. 4 The reactions of CyDTA (trans-1,2-diaminocyclohexane-N, N, N', N '-tetraacetate) with divalent metal ions have been shown6 to fall into two groups. One group including Co(II), Ni(II), (4) D. K. Cabbiness and D. W. Margerum, J. Amer.…”