Transition metal complexes with pyrazole-based ligands. Part 28. Synthesis, structural, DFT and thermal studies of cadmium(II) halides and zinc(II) chloride complexes with 3,5-dimethylpyrazole-1-carboxamidine

Syntheses, structures, and properties of two binuclear cadmium(II) iodides containing a bis(tridentate) Schiff base/tetradentate tripodal amine: control of coordination numbers by varying ligand matrices

“…Research on design and synthesis [1][2][3] of mono-, bi-, and polynuclear coordination compounds of cadmium(II) [4][5][6][7][8][9][10] continues unabated for the preparation of functional materials [11][12][13][14][15] with interesting electronic and optoelectronic properties [15][16][17][18]. Exploiting the diversity in coordination environments around this 4d 10 ion, different metal-organic frameworks [19][20][21] may be accessed using a variety of organic coligands along with different inorganic/organic bridges.…”

“…Exploiting the diversity in coordination environments around this 4d 10 ion, different metal-organic frameworks [19][20][21] may be accessed using a variety of organic coligands along with different inorganic/organic bridges. Polyamines, heterocycles, and Schiff bases are important chelating ligands [22][23][24] in this regard.…”

Zinc(II) and Cadmium(II) complexes with N4-coordinate pyrazole based ligand: Syntheses, characterization and structure

“…But it is not possible to know whether they will act as monodentate or bridging ligand in the bi-and polynuclear complexes. Although a large number of mono, bi-and polynuclear complexes of copper(II), nickel(II) with azide or thiocyanate or isocyanate have been reported, number of papers on zinc(II) and cadmium(II) complexes with pseudohalides are relatively less [15][16][17][18][19][20][21][22]. Among the pseudohalides containing cadmium complexes, the number of isocyanate containing cadmium complexes structurally characterized is rare.…”

Syntheses, molecular and crystalline architectures, and luminescence behaviours of two dinuclear cadmium(II) compounds containing a tetradentate N-donor di-Schiff base

“…Polyamines, heterocycles and Schiff bases are important end-capping ligands [10][11][12] in this regard. Inorganic bridges like halides [13][14][15][16][17] and pseudohalides [18][19][20][21][22][23][24] have been extensively used for the isolation of such metal-organic frameworks. The larger-sized pseudohalide, dicyanamide (dca), is a versatile [21][22][23][24] bridging unit and may bind metal ion through terminal or bridges such as l 1,1, l 1,3, l 1,5 , l 1,1,5, l 1,3,5 , l 3,3,5 and l 1,3,3,5 motifs.…”