2009
DOI: 10.1016/j.poly.2009.08.020
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Transition metal complexes with pyrazole-based ligands. Part 28. Synthesis, structural, DFT and thermal studies of cadmium(II) halides and zinc(II) chloride complexes with 3,5-dimethylpyrazole-1-carboxamidine

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Cited by 27 publications
(13 citation statements)
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“…Research on design and synthesis [1][2][3] of mono-, bi-, and polynuclear coordination compounds of cadmium(II) [4][5][6][7][8][9][10] continues unabated for the preparation of functional materials [11][12][13][14][15] with interesting electronic and optoelectronic properties [15][16][17][18]. Exploiting the diversity in coordination environments around this 4d 10 ion, different metal-organic frameworks [19][20][21] may be accessed using a variety of organic coligands along with different inorganic/organic bridges.…”
Section: Introductionmentioning
confidence: 99%
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“…Research on design and synthesis [1][2][3] of mono-, bi-, and polynuclear coordination compounds of cadmium(II) [4][5][6][7][8][9][10] continues unabated for the preparation of functional materials [11][12][13][14][15] with interesting electronic and optoelectronic properties [15][16][17][18]. Exploiting the diversity in coordination environments around this 4d 10 ion, different metal-organic frameworks [19][20][21] may be accessed using a variety of organic coligands along with different inorganic/organic bridges.…”
Section: Introductionmentioning
confidence: 99%
“…Exploiting the diversity in coordination environments around this 4d 10 ion, different metal-organic frameworks [19][20][21] may be accessed using a variety of organic coligands along with different inorganic/organic bridges. Polyamines, heterocycles, and Schiff bases are important chelating ligands [22][23][24] in this regard.…”
Section: Introductionmentioning
confidence: 99%
“…But it is not possible to know whether they will act as monodentate or bridging ligand in the bi-and polynuclear complexes. Although a large number of mono, bi-and polynuclear complexes of copper(II), nickel(II) with azide or thiocyanate or isocyanate have been reported, number of papers on zinc(II) and cadmium(II) complexes with pseudohalides are relatively less [15][16][17][18][19][20][21][22]. Among the pseudohalides containing cadmium complexes, the number of isocyanate containing cadmium complexes structurally characterized is rare.…”
Section: Introductionmentioning
confidence: 99%
“…Polyamines, heterocycles and Schiff bases are important end-capping ligands [10][11][12] in this regard. Inorganic bridges like halides [13][14][15][16][17] and pseudohalides [18][19][20][21][22][23][24] have been extensively used for the isolation of such metal-organic frameworks. The larger-sized pseudohalide, dicyanamide (dca), is a versatile [21][22][23][24] bridging unit and may bind metal ion through terminal or bridges such as l 1,1, l 1,3, l 1,5 , l 1,1,5, l 1,3,5 , l 3,3,5 and l 1,3,3,5 motifs.…”
Section: Introductionmentioning
confidence: 99%