2016
DOI: 10.1039/c6em00404k
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Transformation of chlorpyrifos and chlorpyrifos-methyl in prairie pothole pore waters

Abstract: Non-point source pesticide pollution is a concern for wetlands in the prairie pothole region (PPR). Recent studies have demonstrated that reduced sulfur species (e.g., bisulfide and polysulfides) in PPR wetland pore waters directly undergo reactions with chloroacetanilide and dinitroaniline compounds. In this paper, the abiotic transformation of two organophosphate compounds, chlorpyrifos and chlorpyrifos-methyl, was studied in PPR wetland pore waters. Chlorpyrifos-methyl reacted significantly faster (up to 4 … Show more

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Cited by 4 publications
(2 citation statements)
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“…Furthermore, pesticides in surface water can be transferred to groundwater through seepage of the soil. They also enter the atmosphere through evaporation and transpiration [175]. Atmospheric water and groundwater can also recharge surface waters.…”
Section: Impact On Watermentioning
confidence: 99%
“…Furthermore, pesticides in surface water can be transferred to groundwater through seepage of the soil. They also enter the atmosphere through evaporation and transpiration [175]. Atmospheric water and groundwater can also recharge surface waters.…”
Section: Impact On Watermentioning
confidence: 99%
“…However, some exceptions exist regarding the dependency of hydrolysis of some pesticides on soil pH. Shabtai and Mishael (2017); Zhang and Pehkonen (1999) reported that rapid hydrolysis of diazinon in both acidic and alkaline conditions followed half-lives of 0.5, 171 and 6 days at a pH DOM) resulted in signi cant reduction on the rate of chlorpyrifos hydrolysis(Adams et al, 2016). The in uence of clay mineral content in degradation of herbicides are also investigated by several researchers(Shabeer et al, 2014) Baglieri et al (2013).…”
mentioning
confidence: 99%