Transesterification activity by a zinc(II)-Schiff base complex with theoretical interpretation

The Crystal Structure and Physicochemical Properties of New Complexes Containing a CuII-LnIII-CuII Core

“…By analyzing the coordination abilities of Schiff bases in terms of the possibility of attaching single metal ions, it can be observed that most Schiff bases formed in the reaction of diamines and their derivatives with o-hydroxyaromatic aldehydes/ketones coordinate a 3d ion in the tetradentate cavity of N 2 O 2 . It is possible to obtain mono- [12,13], di- [14][15][16][17][18], tri- [19,20], tetra- [16,21], and even hexanuclear [22] complexes (Figure 2). In the homodinuclear compounds, the metal:ligand ratio can be 2:1, 2:2, 3:2.…”

In Vitro, In Silico, ADME and Theoretical Analysis of Mn(II) and Co(II) Complexes Derived from Methyl‐(Z)‐N′‐Carbamothioylcarbamohydrazonate Schiff Base Ligand

“…As thione‐thiol tautomers, thiosemicarbazides can coordinate with metal ions neutrally or anionically, depending on whether a proton is lost from thiol‐sulfur (SH) or thio‐amide nitrogen (NH). Thiosemicarbazone based complexes show versatile biological activities against different pathogens [5] such as antibacterial, [6,7] antifungal, [8] antiviral, [9] antitumor, [10] anticancer, [11] antioxidant, [12] antimalarial, [13] insecticidal, [14] antiparasitic, [15] sensing, [16] bio‐catalysis, [17] antihelmintic, [18] and anticonvulsant [19] . Additionally, it has been found that thiosemicarbazones and their analogous compounds are effective against corona‐virus infection (COVID‐19) [20] .…”

Tailor-made isostructural copper(ii) and nickel(ii) complexes with a newly designed (N,N)-donor scaffold as functional mimics of alkaline phosphatase

“…23 The transition metals in coupling with Schiff bases show interesting properties and applications in designing molecular magnets, electrical-transport materials, smart catalysts, efficient chemosensors, etc. 5,6,[24][25][26][27][28] Therefore, scientists are actively engrossed in the design and synthesis of metal complexes along with their functional activities. Copper and nickel metal ions are considered biologically important metal ions.…”