Abstract:In coordination-driven metal−organic cages, the transition metal ions are generally utilized as linkages. Employment of its unique properties with the aim of achieving specific applications still presents great challenges. Herein, we report a decametric metal−organic cage named pentagonal prism (Mn 20 LC 10 ) based on Tpy-Mn(II)-Tpy connectivity (Tpy = 2,2′:6′,2″-terpyridine) in which Mn(II) serves as a linker and endows the resulting metal−organic cage with good photosensitivity. In the photooxidation of benz… Show more
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