Progress in design and applications of supramolecular assembly of 2,2′:6′,2″-terpyridine-based first row d-block elements

Momeni, Badri Z.; Davarzani, Nastaran; Janczak, Jan; Ma, Ning; Abd-El-Aziz, Alaa S.

doi:10.1016/j.ccr.2023.215619

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2023.215619

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Progress in design and applications of supramolecular assembly of 2,2′:6′,2″-terpyridine-based first row d-block elements

Badri Z. Momeni,

Nastaran Davarzani,

Jan Janczak

et al.

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2024

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Cited by 2 publications

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Studies on synthesis and influence of sterically driven Ni(II)-terpyridine (NNN) complexes on BSA/DNA binding and anticancer activity

Panicker,

Sivaramakrishna

2024

Journal of Inorganic Biochemistry

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Studies on synthesis and influence of sterically driven Ni(II)-terpyridine (NNN) complexes on BSA/DNA binding and anticancer activity

Panicker,

Sivaramakrishna

2024

Journal of Inorganic Biochemistry

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Synthesis, characterization and structural analysis of complexes from 2,2′:6′,2′′-terpyridine derivatives with transition metals

Fajardo,

Arteaga,

Ellena

et al. 2024

Acta Crystallogr C

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The synthesis and structural characterization of three families of coordination complexes synthesized from 4′-phenyl-2,2′:6′,2′′-terpyridine (8, Ph-TPY), 4′-(4-chlorophenyl)-2,2′:6′,2′′-terpyridine (9, ClPh-TPY) and 4′-(4-methoxyphenyl)-2,2′:6′,2′′-terpyridine (10, MeOPh-TPY) ligands with the divalent metals Co2+, Fe2+, Mn2+ and Ni2+ are reported. The compounds were synthesized from a 1:2 mixture of the metal and ligand, resulting in a series of complexes with the general formula [M(R-TPY)2](ClO4)2 (where M = Co2+, Fe2+, Mn2+ and Ni2+, and R-TPY = Ph-TPY, ClPh-TPY and MeOPh-TPY). The general formula and structural and supramolecular features were determinated by single-crystal X-ray diffraction for bis(4′-phenyl-2,2′:6′,2′′-terpyridine)nickel(II) bis(perchlorate), [Ni(C21H15N3)2](ClO4)2 or [Ni(Ph-TPY)2](ClO4)2, bis[4′-(4-methoxyphenyl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(perchlorate), [Mn(C22H17N3O)2](ClO4)2 or [Mn(MeOPh-TPY)2](ClO4)2, and bis(4′-phenyl-2,2′:6′,2′′-terpyridine)manganese(II) bis(perchlorate), [Mn(C21H15N3)2](ClO4)2 or [Mn(Ph-TPY)2](ClO4)2. In all three cases, the complexes present distorted octahedral coordination polyhedra and the crystal packing is determined mainly by weak C—H...π interactions. All the compounds (except for the Ni derivatives, for which FT–IR, UV–Vis and thermal analysis are reported) were fully characterized by spectroscopic (FT–IR, UV–Vis and NMR spectroscopy) and thermal (TGA–DSC, thermogravimetric analysis–differential scanning calorimetry) methods.

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Progress in design and applications of supramolecular assembly of 2,2′:6′,2″-terpyridine-based first row d-block elements

Cited by 2 publications

References 335 publications

Studies on synthesis and influence of sterically driven Ni(II)-terpyridine (NNN) complexes on BSA/DNA binding and anticancer activity

Studies on synthesis and influence of sterically driven Ni(II)-terpyridine (NNN) complexes on BSA/DNA binding and anticancer activity

Synthesis, characterization and structural analysis of complexes from 2,2′:6′,2′′-terpyridine derivatives with transition metals

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