Toward an Ideal Synthesis of (Bio)molecules through Direct Arene Assembling Reactions

Yamaguchi, Junichiro; Itami, Kenichiro

doi:10.1246/bcsj.20160365

Cited by 34 publications

(9 citation statements)

References 117 publications

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“…Nanoarchitectonics based on self-assembly relies both on exploration of chemical designs [335,336] and self-assembly processes [337,338]. However, without creation of totally new molecules, the self-assembly processes themselves can open a huge variation of materials possibilities.…”

Section: Future Perspectivesmentioning

confidence: 99%

Self-assembly as a key player for materials nanoarchitectonics

Ariga

Nishikawa

Mori

et al. 2019

Science and Technology of Advanced Materials

354

255

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The development of science and technology of advanced materials using nanoscale units can be conducted by a novel concept involving combination of nanotechnology methodology with various research disciplines, especially supramolecular chemistry. The novel concept is called 'nanoarchitectonics' where self-assembly processes are crucial in many cases involving a wide range of component materials. This review of self-assembly processes reexamines recent progress in materials nanoarchitectonics. It is composed of three main sections: (1) the first short section describes typical examples of self-assembly research to outline the matters discussed in this review; (2) the second section summarizes self-assemblies at interfaces from general viewpoints; and (3) the final section is focused on self-assembly processes at interfaces. The examples presented demonstrate the strikingly wide range of possibilities and future potential of self-assembly processes and their important contribution to materials nanoarchitectonics. The research examples described in this review cover variously structured objects including molecular machines, molecular receptors, molecular pliers, molecular rotors, nanoparticles, nanosheets, nanotubes, nanowires, nanoflakes, nanocubes, nanodisks, nanoring, block copolymers, hyperbranched polymers, supramolecular polymers, supramolecular gels, liquid crystals, Langmuir monolayers, Langmuir-Blodgett films, self-assembled monolayers, thin films, layer-by-layer structures, breath figure motif structures, two-dimensional molecular patterns, fullerene crystals, metal-organic frameworks, coordination polymers, coordination capsules, porous carbon spheres, mesoporous materials, polynuclear catalysts, DNA origamis, transmembrane channels, peptide conjugates, and vesicles, as well as functional materials for sensing, surface-enhanced Raman spectroscopy, photovoltaics, charge transport, excitation energy transfer, lightharvesting, photocatalysts, field effect transistors, logic gates, organic semiconductors, thin-film-based devices, drug delivery, cell culture, supramolecular differentiation, molecular recognition, molecular tuning, and hand-operating (hand-operated) nanotechnology.

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Section: Future Perspectivesmentioning

confidence: 99%

Self-assembly as a key player for materials nanoarchitectonics

Ariga

Nishikawa

Mori

et al. 2019

Science and Technology of Advanced Materials

354

255

View full text Add to dashboard Cite

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“…Although various scientific disciplines have contributed to developments in functional materials, there is a common consensus concerning methodologies to create functional materials, such as (i) the design, synthesis, and functionalization of unit molecules and materials [1][2][3][4][5][6][7] and (ii) the rational organization of synthesized units into functional architectures [8][9][10][11][12][13][14][15] . Regulation of nanoscale structures and their organization is crucial to synthesize functional materials.…”

Section: Introductionmentioning

confidence: 99%

Soft 2D nanoarchitectonics

et al. 2018

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Nanoarchitectonics is a new paradigm to combine and unify nanotechnology with other sciences and technologies, such as supramolecular chemistry, self-assembly, self-organization, materials technology for manipulation of the size of material objects, and even biotechnology for hybridization with bio-components. The nanoarchitectonic concept leads to the synergistic combination of various methodologies in materials production, including atomic/molecularlevel control, self-organization, and field-controlled organization. The focus of this review is on soft 2D nanoarchitectonics. Scientific views on soft 2D nanomaterials are not fully established compared with those on rigid 2D materials. Here, we collect recent examples of 2D nanoarchitectonic constructions of functional materials and systems with soft components. These examples are selected according to the following three categories on the basis of 2D spatial density and motional freedom: (i) well-packed and oriented organic 2D materials with rational design of component molecules and device applications, (ii) well-defined assemblies with 2D porous structures as 2D network materials, and (iii) 2D control of molecular machines and receptors on the basis of certain motional freedom confined in two dimensions.

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“…Nanoarchitectonics may be a good navigator for evolution from materials to life activities 117 as well as design and constructions of highly advanced bioactive functional materials systems. Not limited to bio-related systems, 452,453 the ways of materials construction by nanoarchitectonics would become nice guides for developments of functional systems in chemistry including synthesis of novel molecules, 454,455 fabrication and functionalization of low-dimensional materials, 456,457 and construction of hybrid materials, 458 and others.…”

Section: Resultsmentioning

confidence: 99%

Chemistry Can Make Strict and Fuzzy Controls for Bio-Systems: DNA Nanoarchitectonics and Cell-Macromolecular Nanoarchitectonics

Komiyama

Yoshimoto

Sisido

et al. 2017

Bulletin of the Chemical Society of Japan

276

131

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In this review, we introduce two kinds of bio-related nanoarchitectonics, DNA nanoarchitectonics and cellmacromolecular nanoarchitectonics, both of which are basically controlled by chemical strategies. The former DNA-based approach would represent the precise nature of the nanoarchitectonics based on the strict or "digital" molecular recognition between nucleic bases. This part includes functionalization of single DNAs by chemical means, modification of the main-chain or side-chain bases to achieve stronger DNA binding, DNA aptamers and DNAzymes. It also includes programmable assemblies of DNAs (DNA Origami) and their applications for delivery of drugs to target sites in vivo, sensing in vivo, and selective labeling of biomaterials in cells and in animals. In contrast to the digital molecular recognition between nucleic bases, cell membrane assemblies and their interaction with macromolecules are achieved through rather generic and "analog" interactions such as hydrophobic effects and electrostatic forces. This cell-macromolecular nanoarchitectonics is discussed in the latter part of this review. This part includes bottom-up and top-down approaches for constructing highly organized cell-architectures with macromolecules, for regulating cell adhesion pattern and their functions in twodimension, for generating three-dimensional cell architectures on micro-patterned surfaces, and for building synthetic/natural macromolecular modified hybrid biointerfaces.

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Toward an Ideal Synthesis of (Bio)molecules through Direct Arene Assembling Reactions

Cited by 34 publications

References 117 publications

Self-assembly as a key player for materials nanoarchitectonics

Self-assembly as a key player for materials nanoarchitectonics

Soft 2D nanoarchitectonics

Chemistry Can Make Strict and Fuzzy Controls for Bio-Systems: DNA Nanoarchitectonics and Cell-Macromolecular Nanoarchitectonics

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