energy from nature and the human body, and to power billions of distributed electronics and sensor networks. [1,2] Compared with traditional energy generators, TENG has demonstrated great advantages in efficiency, flexibility, lightweight, environmentally friendly, and environmental adaptability. [3][4][5] As a brand-new invention by Z. L. Wang in 2012, [6] TENG takes a tremendous advancement in various aspects, such as triboelectric mechanism, [7][8][9] structure optimization, [10,11] material research, [12][13][14] application extension, [15][16][17][18] output power, [19,20] direct current (DC) TENG, [21][22][23] and power management system (PMS). [24] However, TENG still has some problems to be addressed. For example, the energy-transfer efficiency from TENG to loads in real applications is not optimal. The reason is that TENG always mismatches with the impedance of load when directly powering electronics or storing electricity generated by the triboelectrification effect. Fortunately, as a bridge between TENG and electronics to reduce the mismatch and improve the energy-transfer efficiency, [24] PMS is invented. Consisting of a temporary storage capacitor (C t ), a switch, and a buck circuit, [25][26][27][28][29] PMS converts random energy from TENG into a steady DC power supply for driving electronics in high efficiency. For example, with and without a high-performance PMS in practical applications, the speed of energy storage in a capacitor can differ by two orders of magnitude. [30] Furthermore, the improvement is reported many times, such as quickly starting up and simultaneously driving multiple devices. [25,28,30,31] The remarkable value of PMS has attracted a lot of attention and leads to various designs, following the same principle and similar topological structures but with different switch designs. [24,25,28] The study of switches, as the key component of PMS, becomes the main effort. In the early stage of switch development (from 2013), reported switches start the PMS field but are bounded together with and followed the movement of TENG, indicating the lowest adaptability in applications. [27,30,[32][33][34][35][36] In the next development stage (from 2015), to investigate the principle of PMS, many active electronic switches are proposed and studied. [25,28,29] Using metal-oxide Triboelectric nanogenerators (TENGs) are used to harvest high entropy energy. To optimize the energy harvesting, storage and effective utilization, a critical part is the power management system (PMS), which requires an ideal electrical switch as the key component. However, the current switch technologies cannot adapt and enhance the charging for the four operation modes of TENG simultaneously. Herein, a flexible film-discharge-switch (FDS), delivering an averaged charge-enhance factor over 100 under four operation modes of TENG, compared to directly charging a capacitor with conventional rectifier is reported. More specifically, the charge-enhancement factors of the FDS are 134.3, 64.7, 97.0, and 136.5 for the modes of ...