Surface charge density
(σSC) is essential
to the output of the triboelectric nanogenerator (TENG). Massive efforts
have been made to improve it, which can be totally categorized into
four types. Two of them are utilized to optimize the basic electrification
of the TENG, and the other two are for the device configuration and
following circuits. However, the basic electrification of the 100
μm-thick film under ambient conditions still stays below 200
μC m–2. Herein, we proposed a brand-new technical
route, by designing an asymmetric-internal-capacitance configuration,
which forms a “hot surface” rich in free electrons at
the electrification interface and finally promotes σSC to 550 μC m–2. Specifically, σSC of Cu is improved by 35 times, reaching 9.48 times that
of nylon that is reported to be a strong positive triboelectric material.
Furthermore, the hot
surface improves the output of the TENG by 12.8 times and drives multiple
devices floating in water to work stably, showing great potential
in harvesting water wave energy (blue energy).