Positron-annihilation / Alkali-metal-fulleride / Thermal-desorption / Raman-shiftSummary. Hydrogen-doped alkali-metal fullerides were studied by means of mass-analyzed thermal desorption and positron annihilation. The hydrogen desorption spectra reveal the inclusion of hydrogen in the fullerides as two types of components; one weakly adsorbed and the other strongly bound, probably as hydride ion. The positron lifetime spectra demonstrate that hydrogen-doping to alkali-metal fullerides increases a concentration of higher-order vacancy-type defects, through which more than 50% injected positrons decay with a lifetime of 0.42-0.71 ns.