2010
DOI: 10.1002/elan.201000491
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Thin‐Film Voltammetry of a Lutetium Bisphthalocyanine at Ionic Liquid|Water Interface

Abstract: At room temperature, tetraoctylphosphonium bromide is a viscous ionic liquid, this gel-like organic phase can be cast over a basal-plane graphite electrode (BPGE). Cyclic voltammetry at such a modified electrode, in contact with an aqueous solution have revealed one reversible oxidation and five reversible reduction steps for a Lu III bisphthalocyanine dissolved in the ionic liquid film, a proof that the highly reactive reduced species were protected from interaction with water in this highly lipophilic phase.… Show more

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Cited by 7 publications
(2 citation statements)
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“…At this level, we cannot establish the fact that the system I/I exchanges one electron. In order to shed more light on these systems and gather more information (e.g., the number of the electrons exchanged), some few experiments were done using square wave voltammetry, a more sensitive method especially when one deals with membrane processes [26][27][28][29][30]. The SWV technique is one of the most advanced voltammetric methods unifying the advantages of CV and pulse voltammetric techniques.…”
Section: Resultsmentioning
confidence: 99%
“…At this level, we cannot establish the fact that the system I/I exchanges one electron. In order to shed more light on these systems and gather more information (e.g., the number of the electrons exchanged), some few experiments were done using square wave voltammetry, a more sensitive method especially when one deals with membrane processes [26][27][28][29][30]. The SWV technique is one of the most advanced voltammetric methods unifying the advantages of CV and pulse voltammetric techniques.…”
Section: Resultsmentioning
confidence: 99%
“…Among others, the model developed in this Brief Report is relevant for all situations in which a thin electrolyte film covers a wall in the presence of a second immiscible electrolyte. Examples are electrochemical setups utilizing electrodes covered by a thin liquid film [10][11][12], for which the rate of electrode reactions is dictated by the EDL structure at the electrode surface (see [13] and references therein).…”
mentioning
confidence: 99%