1977
DOI: 10.1002/apmc.1977.050600101
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Thermoplastische Elastomere auf Polyolefinbasis mit kristallinen Segmenten

Abstract: ZUSAMMENFASSUNG:Athylen-Propylen-Copolymere (EPM) werden mit dem loslichen Ziegler-Natta-Katalysator VOCl3/Al2 (C2H=J3Cl3 in Hexan kontinuierlich bei 50°C hergestellt. In Gegenwart von Perchlorcrotonsaureestern CC13-CC1=CC1-COOR (R = CH3, C4H9) als Reaktivator entstehen bei geringer Vanadium-Konzentration in hohen Ausbeuten Copolymere, die bis zu 17 Gew.-% kristalline fCHz-CH2+,-Segmente enthalten und giinstige Roheigenschaften zeigen. Ein gesattigtes Terpolymeres aus Athylen, Propylen und 15 % Bicyclo(2,2,1 )… Show more

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Cited by 15 publications
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“…The decrements in activity which are observed under certain conditions are due to the reduction of vanadium to VII, which may be reactivated by the addition of weak oxidizing agents [215,408].…”
Section: Catalytic Complexes: Concentration Valence Of Vanadiummentioning
confidence: 99%
“…The decrements in activity which are observed under certain conditions are due to the reduction of vanadium to VII, which may be reactivated by the addition of weak oxidizing agents [215,408].…”
Section: Catalytic Complexes: Concentration Valence Of Vanadiummentioning
confidence: 99%