2011
DOI: 10.1016/j.molliq.2011.09.002
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Thermophysical properties of binary mixtures (dimethyl carbonate+ketones) at T=(303.15, 308.15 and 313.15)K

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Cited by 36 publications
(10 citation statements)
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“…As for the variation of Δ G E with the molar fraction, the values are mostly positive, with the exception of mixtures close to extreme composition. Positive values of this magnitude are indicative of the dominance of specific interactions among the molecules of the compounds in the binary mixture, whereas negative values denote that dispersion forces prevail . Here, the effect of an increase of the temperature resulted in lower values of Δ G E .…”
Section: Results and Correlationsmentioning
confidence: 94%
See 3 more Smart Citations
“…As for the variation of Δ G E with the molar fraction, the values are mostly positive, with the exception of mixtures close to extreme composition. Positive values of this magnitude are indicative of the dominance of specific interactions among the molecules of the compounds in the binary mixture, whereas negative values denote that dispersion forces prevail . Here, the effect of an increase of the temperature resulted in lower values of Δ G E .…”
Section: Results and Correlationsmentioning
confidence: 94%
“…The positive V E values are thought to be caused by packing effects in the mixture, with an increasing presence of cetane leading to the disruption of the hydrogen bonding that may form among solketal molecules. The negative values, for their part, may be caused by packing of oversized molecules, which can result in interstitial void space that becomes filled by smaller molecules . As for the effect of the temperature, an increase causes the hydrogen bonds to break, which is the reason why the values are more and more positive as this variable increases …”
Section: Results and Correlationsmentioning
confidence: 99%
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“…In continuation of our program of research on the physicochemical properties of binary nonelectrolyte liquid mixtures of esters [4][5][6]. We report here experimental densities (), viscosities (), and refractive indices (n D ) for dibutyl maleate + acetophenone, + cyclopentanone, + cyclohexanone and + 3-pentanone at (303.15, 308.15 and 313.15) K over the entire range of mixture composition at atmospheric pressure.…”
Section: Introductionmentioning
confidence: 99%