Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties

Žemva, Boris; Lutar, K.; Chacón, L.; Fele‐Beuermann, M.; Allman, J.; Shen, C.; Bartlett, Neil

doi:10.1021/ja00145a013

Cited by 74 publications

(45 citation statements)

References 2 publications

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“…Thus, AgF 2 was successfully applied as a fluorinating agent towards a range of inorganic and organic compounds, and it ranks second to none among common superior fluorinetransfer catalysts (AgF 2 > XeF 2 > CoF 3 > NiF 2 , etc.) [13]. Such reactions may simply be conducted in a stream of F 2 gas, with a trace amount of Ag 1+ as a catalyst precursor (AgF 2 forms in situ).…”

mentioning

confidence: 99%

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Grochala

2017

J Supercond Nov Magn

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In this personal account, the author takes readers on the journey to "Silverland," i.e., the emerging field of electronic and magnetic materials based on divalent silver (Ag 2+ ). He blends historical background with the reasons which led him to become involved in this research, as well as to proposing (with Roald Hoffmann, 2001) that high-T C superconductivity might ultimately be observed in doped Ag 2+ fluorides. More recent experimental and theoretical findings related to novel compounds, and their electronic and magnetic structure, are presented.

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confidence: 99%

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Grochala

2017

J Supercond Nov Magn

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“…Removal of As was also performed via oxidation by K 2 NiF 6 , which is a very strong oxidizer of Ni(IV) [11,12]. The process is based on the following equation (Eq.…”

Section: Oxidation By K 2 Nifmentioning

confidence: 99%

Elimination of AsF3 from anhydrous HF using AgFAsF6 as a mediator

Matsumoto

Hagiwara

2010

Journal of Fluorine Chemistry

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“…High-valence nickel fluorides are not soluble in HF [24]. Hence the fluorination in HF is a heterogeneous process taking place on the surface of the Ni anode.…”

Section: Nickel Metalmentioning

confidence: 99%

Industrial Electrocatalysis

Kotrel

Bräuninger

2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction: From Industrial Electrochemistry to Electrocatalysis Catalysis in Organic Electrochemistry Synthesis of Adiponitrile The S imons Process Bleached Montan Wax—Regeneration of Chromic Acid Waste Water Treatment A Anodic Oxidation of Toxic compounds a Creating Reactive Oxygen Surface Species b Selective Conversion vs. Total Combustion c Common Electrode Materials B Cathodic Reduction of Toxic Compounds Catalysis in Inorganic Electrochemistry Chloralkali Electrolysis A Electrocatalytically Activated Dimensionally Stable Chlorine‐Evolving Electrodes ( DSAs ) B Electrocatalysis of Anodic Chlorine Evolution at Ru O 2 Anodes C Details of the Electrocatalytic Process D Preparation and Formulation of the Coatings for DSAs E Lifetime of Dimensionally Stable Chlorine‐Evolving Anodes F The Cathode Reaction—Oxygen‐Depolarized Cathode ( ODC ) Electrolysis of Hydrochloric Acid Preparation of Oxygen‐Depolarized Cathodes First Industrial HCl Electrolysis Using ODCs Oxygen‐Depolarized Cathodes for Chloralkali Electrolysis Industrial Water Electrolysis A The Electrochemistry of Water Electrolysis B Alkaline Water Electrolysis C PEM Water Electrolysis D High‐Temperature Water Electrolysis Summary and Outlook

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Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties

Cited by 74 publications

References 2 publications

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Elimination of AsF3 from anhydrous HF using AgFAsF6 as a mediator

Industrial Electrocatalysis

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