Thermodynamic Properties of Liquid Silver-Tin Alloys

Kameda, Kazuo; Yoshida, Yoshio; Sakairi, Senzi

doi:10.2320/jinstmet1952.44.8_858

Cited by 14 publications

(8 citation statements)

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“…12 along with experimental data. [62,63,65,66,[68][69][70][71]82] According to our [88,89] calculations, the hcp phase is formed from the peritectic reaction liquid + fcc M hcp at 724°C, which is identical to the experimental data reported by Murphy. [65] The Ag 3 Sn binary compound was treated as a solid solution with a two sub-lattice model as (Ag, Sn) 3 (Sn).…”

Section: 21supporting

confidence: 79%

“…The activity of Sn in the liquid phase at 827 and 727°C were determined by Iwase et al [81] using the emf measurements method with two different solid-oxide galvanic cells. And the derived activity of Sn in liquid solution in the work of Iwase et al [81] are self-consistent, but are not in agreement with the previous reported results [73,79,80] The activity of Sn in the liquid phase at 600 and 700°C were measured by Kameda et al [82] using the emf measurements method. The enthalpy of formation of solid phases were measured by Flandorfer et al [83] with calorimetric measurements method.…”

Section: Ag-sn Systemmentioning

confidence: 67%

“…% Fig. 11 Calculated heat formation of solid phases of Ag-In system at 25°C compared with experimental data [49,58] Sn / at.% Peternko [63] Murphy [65] Hume-Rothery et al [66] Umansky [70] Hanson et al [68] Owen and Roberts [69] Kameda et al [82] Vnuk et al [71] Temperature, C o Fig. 12 Calculated phase diagram of Ag-Sn system compared with experimental data [62,63,65,66,[68][69][70][71]82] Fig.…”

Section: Methodsmentioning

confidence: 99%

“…11 Calculated heat formation of solid phases of Ag-In system at 25°C compared with experimental data [49,58] Sn / at.% Peternko [63] Murphy [65] Hume-Rothery et al [66] Umansky [70] Hanson et al [68] Owen and Roberts [69] Kameda et al [82] Vnuk et al [71] Temperature, C o Fig. 12 Calculated phase diagram of Ag-Sn system compared with experimental data [62,63,65,66,[68][69][70][71]82] Fig. 13 Calculated mixing of enthalpy of liquid phase of Ag-Sn system at 1000°C compared with experimental data [53,75,78,84,85] Liquidus and polymorphic transformation temperatures were measured by differential scanning calorimetry (DSC) using the SETARAM instrumentation under a continuous flow of purified argon at Concordia University.…”

Section: Methodsmentioning

confidence: 99%

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Thermodynamic and Experimental Study of the Mg-Sn-Ag-In Quaternary System

Wang

Hudon

Kevorkov

et al. 2014

J. Phase Equilib. Diffus.

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Phase equilibria in the Mg-rich region of the Mg-Sn-Ag ternary system were determined by quenching experiments, differential scanning calorimetry, electron probe micro-analysis, and Xray diffraction techniques. No ternary compounds were found in the studied isothermal sections. A critical evaluation of the available experimental data and a thermodynamic optimization of the Mg-Sn-Ag-In quaternary system were carried out using the calculation of phase diagrams method. The modified quasichemical model in the pair approximation was used for the liquid solution, which exhibits a high degree of short-range order. The solid phases were modeled with the compound energy formalism. All available and reliable experimental data were reproduced within experimental error limits. A self-consistent thermodynamic database was constructed for the Mg-Sn-Ag-In quaternary system, which can be used as a guide for Mg-based alloys development.

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Section: 21supporting

confidence: 79%

Section: Ag-sn Systemmentioning

confidence: 67%

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

See 2 more Smart Citations

Thermodynamic and Experimental Study of the Mg-Sn-Ag-In Quaternary System

Wang

Hudon

Kevorkov

et al. 2014

J. Phase Equilib. Diffus.

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show abstract

“…Chowdhury and Ghosh, 33 Kubaschewski and Alcock, 34 Seetharaman and Staffansson, 35 Iwase et al 36 and Kameda et al 37 demonstrated that the activity of tin exhibits negative deviation from Raoult's Law, which is almost insignificant for tin-rich alloys and deviates visibly for X Ag approaching pure silver.…”

Section: Discussionmentioning

confidence: 99%

Thermodynamic Properties of Liquid Silver-Antimony-Tin Alloys Determined from Electrochemical and Calorimetric Measurements

Łapsa¹,

Onderka²

2016

Journal of Elec Materi

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The thermodynamic properties of liquid Ag-Sb-Sn alloys were obtained through use of the drop solution calorimetric method and electromotive force (emf) measurements of galvanic cells with a yttria stabilized zirconia (YSZ) solid electrolyte. The experiments were carried out along Ag 0.25 Sb 0.75 , Ag 0.5 Sb 0.5 and Ag 0.75 Sb 0.25 sections of the ternary system in the temperature range from 973 K to 1223 K. From the measured emf, the tin activity in liquid solutions of Ag-Sb-Sn was determined for the first time. The partial and integral enthalpy of mixing were determined from calorimetric measurements at two temperatures. These measurements were performed along two crosssections: Sb 0.5 Sn 0.5 at 912 K and 1075 K, and Ag 0.75 Sb 0.25 at 1075 K. Both experimental data sets were used to find ternary interaction parameters by applying the Redlich-Kister-Muggianu model of the substitutional solution. Consequently, the set of parameters describing the thermodynamic properties of the liquid phase was derived.

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Enthalpies of Formation at 1373 K of the Liquid Alloys Ag + Au, Ag + Sn, Au + Sn and Ag + Au + Sn

Rakotomavo

Gaune‐Escard

Bros

et al. 1984

Ber Bunsenges Phys Chem

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The enthalpies of formation ΔHM of the liquid binary (Ag + Au, Ag + Sn and Au + Sn) and ternary alloys (Ag + Au + Sn) were measured at 1373 K by direct calorimetry on the whole concentration range. The ternary investigations were conducted along the sections XAg/XAu = 1/4, 1/1, 6.25/3.75 and 7/3 with XSn < 0.60 and XAg/XSn = 3/7, 1/1 and 7/3 with XAu < 0.60. The apparatus used was a very high temperature calorimeter with a sensing device consisting in 20 Pt + 6% Rh/Pt + 30% Rh thermocouples. The experimental uncertainty was quoted at 10%. The results obtained for the limiting binary systems were compared with those, numerous and contradictory, reported in literature. The enthalpies of formation of the ternary alloys Ag + Au + Sn can be represented using a modified Kohler's equation including a supplementary correction term to the binary contributions.

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Thermodynamic Properties of Liquid Silver-Tin Alloys

Cited by 14 publications

References 0 publications

Thermodynamic and Experimental Study of the Mg-Sn-Ag-In Quaternary System

Thermodynamic and Experimental Study of the Mg-Sn-Ag-In Quaternary System

Thermodynamic Properties of Liquid Silver-Antimony-Tin Alloys Determined from Electrochemical and Calorimetric Measurements

Enthalpies of Formation at 1373 K of the Liquid Alloys Ag + Au, Ag + Sn, Au + Sn and Ag + Au + Sn

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