Thermodynamic and thermal properties of the C 60 - l -lysine derivative

Lelet, Maxim I.; Semenov, Konstantin N.; Andrusenko, Elena V.; Чарыков, Н. А.; Murin, I. V.

doi:10.1016/j.jct.2017.07.017

Cited by 15 publications

(1 citation statement)

References 39 publications

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“…This article continues the cycle of publications, concerning the synthesis, identification and physico-chemical, physical, bio-chemical, biological properties investigation of the amino-acid-light fullerene adducts [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19]. This article is devoted to the investigation of the solubility diagram for systems containing water soluble fullerene nanoclusters, inorganic salt, including rare earth metals and actinoids, and water, as the solvent [20][21][22][23][24].…”

Section: Introductionmentioning

confidence: 99%

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Glushnev¹,

Kanbar²,

Кескинов³

et al. 2020

Nanosystems: Phys. Chem. Math.

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Solubility diagram was investigated by the method of saturation in ampules at 25 ± 0.02 • C for 4 hours. The solubility diagram of the PrCl 3-C 60 (OH) 24-H 2 O ternary system at 25 • C occurs as simple eutonics, consisting of two branches, corresponding to the crystallization of crystalhydrates: PrCl 3 • 7H 2 O and C 60 (OH) 24 • 18H 2 O. The diagram contains one non-variant point each-eutonics, which corresponds to saturation with pair of crystal-hydrates simultaneously. The diagram also contains very short branch of PrCl 3 • 7H 2 O crystallization, and long branch of C 60 (OH) 24 • 18H 2 O, where the effect of fullerenol salt-out is distinctly observed.

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Section: Introductionmentioning

confidence: 99%

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Glushnev¹,

Kanbar²,

Кескинов³

et al. 2020

Nanosystems: Phys. Chem. Math.

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Highly Sensitive and Selective Sensors for CF₄ Gas Molecules Based on Two‐Node Hollow Fullerene

Zhang

Feng

et al. 2020

Adv Materials Inter

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assemblies and nanofunctional materials in the field of optoelectronic devices, catalysis, biomedicines, and so on. [4] On one hand, C 60 has a triple degenerate lowest unoccupied molecule orbital (LUMO), presenting a good electron-accepting ability for holding up to six electrons and facilitating the formation of donor-acceptor dyads. On the other hand, it can be viewed as electron-deficient polyalkene and, therefore, chemically reactive. [5] These two features make the derivatization of fullerene feasible so as to extend its functionality. Various kinds of molecules/ structures have been linked to fullerenes to form fullerenes derivatives. For example, biphenyl fulleroids (Ph 2 C 61) was first synthesized by Suzuki et al. in 1991, [6] which was followed soon by the synthesis of Phenyl-C61-butyric acid methyl ester (PC 61 BM). [7] The latter was demonstrated advantageous in organic photovoltaics (OPVs) by enhancing the open-circuit voltage. [8] Meanwhile, physical and chemical modifications of fullerene have been achieved by linking to other molecular structures. By combining the distinctive features of fullerenes and unique physical properties of the linked molecules, advanced fullerene derivative materials with novel physicochemical characteristics can be synthesized. Some of these fullerene derivative materials have been demonstrated to possess great electrical, [9] thermal, [10] optical, [11] photovoltaic, [12] and solubility properties, [12] which could be applied in photovoltaic, [13] optical, [10c] and temperature sensors. [14] The cage-shaped space of fullerene derivatives can be used to trap small molecules. These small molecules, in turn, modify the electronic properties of the fullerene derivatives, leading to various structures of the fullerene derivatives with peculiar and exceptional phenomenon. The design and development of such molecular containers with a discrete structure for the uptake of small molecules represent attractive research targets. Recently, the synthesis of open-cage fullerene with a circular 17-membered-ring opening, which contains one sulfur atom on the rim, was reported. [15] Murata and co-workers trapped N 2 and CO 2 molecules in the confined internal sub-nano spaces of the open-cage fullerene derivatives. Subsequently, by encapsulating a NO molecule into an open-cage fullerene derivative, a metal-free electron spin system was successfully constructed. [16] The synthetic methods to insert small molecules into fullerene derivatives have been extensively studied. [17] Very recently, Han et. al., synthesized a variety of hollow C 60 nanostructures, using the xylene template, with tailored shapes, such as two-node calabash. [18] This methodology not only expands the synthetic Hollow nanostructures are widely used in chemistry, materials, and bioscience due to their excellent electrochemical and photoelectric properties. Recently, hollow fullerene nanostructures with tailored opening and shapes have been synthesized. Here, the transport properties of two-node hollow-fullerene-based ...

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Biocompatibility and biological activity of C70 fullerene adduct with L-threonine (C70(C4H9NO3)2)

Sharoyko

Serebryakov

Ageev

et al. 2022

Biochemical and Biophysical Research Communications

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Thermodynamic and thermal properties of the C 60 - l -lysine derivative

Cited by 15 publications

References 39 publications

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Highly Sensitive and Selective Sensors for CF₄ Gas Molecules Based on Two‐Node Hollow Fullerene

Biocompatibility and biological activity of C70 fullerene adduct with L-threonine (C70(C4H9NO3)2)

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Thermodynamic and thermal properties of the C 60 - l -lysine derivative

Cited by 15 publications

References 39 publications

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Solubility phase equilibrium in ternary system fullerenol C60(OH)24 and praseodymium salt: PrCl3-C60(OH)24-H2O at 25 C

Highly Sensitive and Selective Sensors for CF4 Gas Molecules Based on Two‐Node Hollow Fullerene

Biocompatibility and biological activity of C70 fullerene adduct with L-threonine (C70(C4H9NO3)2)

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Highly Sensitive and Selective Sensors for CF₄ Gas Molecules Based on Two‐Node Hollow Fullerene