Thermochemistry of molybdenum hexacarbonyl and molybdenum triiodide

Barnes, David S.; Pilcher, G.; Pittam, D.A.; Skinner, H. A.; Todd, D.; Virmani, Y.

doi:10.1016/0022-5088(74)90098-8

Cited by 16 publications

(2 citation statements)

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“…49 ' 50 , since for each substance they obtained results in good agreement by two different methods. Table 5 gives recommended 53 enthalpies of sublimation.…”

Section: Chromium Molybdenum and Tungsten Hexacarbonylsmentioning

confidence: 83%

“…Analysis of the solid products revealed 48 that the oxides were accompanied by a certain quantity of unoxidised metal, which entailed appropriate corrections to the enthalpies of formation. The above results 47 ' 48 have recently been carefully checked by Skinner et al 49 " 51 , using not only combustion in a stationary bomb but also their calorimetric methods of thermal decomposition and high-temperature iodination. Table 4.…”

Section: Chromium Molybdenum and Tungsten Hexacarbonylsmentioning

confidence: 97%

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Thermochemistry of Organic Compounds of Transition Metals

Tel'noi¹,

Rabinovich²

1977

Russ. Chem. Rev.

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Experimental enthalpies of formation of carbonyl, cyclopentadienyl, arene, and alkoxyl compounds of transition metals are discussed with methods for their determination. Mean dissociation energies calculated therefrom for the bonds formed by the metals in these compounds vary regularly with the nature of the ligand and the position of the metal in the Periodic System. All the thermochemical quantities cited have been recalculated on the basis of current values of the initial data. A list of 112 references is included.Methods for calculating values of D in compounds RML are described in connection with specific compounds. *Here and subsequently: g = gaseous state; 1 = liquid state; c = crystalline state; and s = solution.

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“…49 ' 50 , since for each substance they obtained results in good agreement by two different methods. Table 5 gives recommended 53 enthalpies of sublimation.…”

Section: Chromium Molybdenum and Tungsten Hexacarbonylsmentioning

confidence: 83%

Section: Chromium Molybdenum and Tungsten Hexacarbonylsmentioning

confidence: 97%