Thermochemistry of Benzenamine Adducts of Arsenic Trihalides

Dunstan, P.O.

doi:10.1021/je00016a005

Search citation statements

Order By: Relevance

Paper Sections

Select...

Results1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1995

1999

Publication Types

Select...

Article4

Relationship

Self Cite1

Independent3

Authors

Journals

Cited by 4 publications

(1 citation statement)

References 14 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Endothermic peaks due to decompositon and elimination of part of trihalide and part of ligand together are also observed. Exothermic peaks due to the redox degradation of the ligand are also observed (Dunstan, 1994a(Dunstan, ,b, 1995(Dunstan, , 1996. Table 3 presents the thermoanalytical data of the adducts.…”

Section: Resultsmentioning

confidence: 91%

Thermochemistry of Adducts of Arsenic Trihalides with Saturated Heterocyclic Bases

Dunstan

1996

J. Chem. Eng. Data

Self Cite

View full text Add to dashboard Cite

The adducts AsX3·nL (where L is piperazine (Pipz), morpholine (Morph), or piperidine (Pipd); X is Cl, Br, or I; and n is 1, 3/2, or 2) have been synthesized and characterized by melting points, elemental analysis, thermal studies, and infrared spectroscopy. By means of calorimetric measurements in solution, the mean standard enthalpies of the arsenic−nitrogen bonds were determined as well as the values of other thermochemical parameters of the adducts.

show abstract

Section: Resultsmentioning

confidence: 91%