Thermochemistry of aniline derivatives complexes of arsenic trihalides

Dunstan, P.O.

doi:10.1016/0040-6031(95)02418-2

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1996

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Cited by 5 publications

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“…Only in the case of AsBr 3 ‚Morph was a third step observed with elimination of the rest of AsBr 3 . Only in the case of AsI 3 ‚2Morph was a residue, probably carbon, observed (Dunstan, 1995). The DSC curves of the morpholine adducts that are consistent with the TG data showed several peaks.…”

Section: Resultssupporting

confidence: 77%

Thermochemistry of Adducts of Arsenic Trihalides with Saturated Heterocyclic Bases

Dunstan

1996

J. Chem. Eng. Data

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The adducts AsX3·nL (where L is piperazine (Pipz), morpholine (Morph), or piperidine (Pipd); X is Cl, Br, or I; and n is 1, 3/2, or 2) have been synthesized and characterized by melting points, elemental analysis, thermal studies, and infrared spectroscopy. By means of calorimetric measurements in solution, the mean standard enthalpies of the arsenic−nitrogen bonds were determined as well as the values of other thermochemical parameters of the adducts.

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Section: Resultssupporting

confidence: 77%