a b s t r a c tIn this study, calcium fluoride (CaF 2 ) thin films have been prepared by Thermionic Vacuum Arc (TVA) technique on glass substrates. In this technique CaF 2 thin films are produced by condensing the plasma of anode material generated in the TVA setup under high vacuum conditions on glass substrates. Crystal structures as well as optical and surface properties of CaF 2 antireflective (AR) coated thin films were investigated. X-ray diffraction (XRD) measurements showed that amorphous CaF 2 thin films were formed. Optical and surface properties of CaF 2 films have been studied based on optical transmittance, reflectance, refractive index and atomic force microscopy imaging (AFM). Our results also show that CaF 2 coated samples exhibit lower reflectance (R). From our optical studies, we have observed that CaF 2 thin films have high AR properties.