Based on atomic first principles, we predict enhanced thermal spin transfer (TST) effects and small switching temperature gradient in Fe | MgO | Fe | MgO | Fe double-barrier magnetic tunnel junctions (MTJs). At room temperature, temperature gradient DT ∼10 K with T ∼10 K nm −1 across barriers would be sufficient to switch the magnetic configurations circularly in a junction with 3 MgO atomic layers (L), which is about one order smaller than that in Fe | MgO(3L)| Fe MTJs. This temperature gradient is under the current experimental capability. The resonant quantum-well states in companion with resonant interfacial states are responsible for the enhancement. Moreover, a thermal induced 'off ' state is found in a double-barrier MTJ.