“…Now-a-days, such perovskites have been widely explored because of their diverse pompous physical as well as electrochemical attributes [1][2][3][4][5][6]. These types of perovskites are also tremendously used as magnetic memories, nonlinear optics, magneto-optic, magneto-ferroics, thermoelectric properties, tunnel junctions, and additional magnetic devices in the unprecedented spintronic arena [11,12]. An exceptional ordering in the A-site atoms results in an A-site ordered perovskite-structure oxide with the formula AA′ 3 B 4 O 12 where the A and A′ ions are in the ordered state [13] is called quadruple perovskite also.…”