Rates of mass transfer by free convection have been measured for spheres of three organic acids dissolving in three solvents, water, n-butanol and benzene. The results fell into two groups, one in which flow is completely laminar and one in which turbulence had set in in the boundary layer. Turbulence appears to set in a t N' Ra 1 t c 6 x lo*.Little work has been carried out on mass transfer by free convection from solid spheres, and usually it is treated by analogy with heat transfer. The present work was designed to measure mass transfer rates over a wide range of the relevant variables and to provide data for comparison with mass transfer at very low flow rates. A series of systems (benzoic acid in water, succinic acid in n-butanol, succinic acid in acetone, and salicylic acid in benzene) was chosen to give a wide variation in Schmidt and Grashof numbers. (1) = f ( N z , , N s e ) Schmidt and Beckman (10) suggested that the problem could be attacked by means of boundary-layer theory. For this method to be applicabIe all viscous and concentration effects must be restricted to a thin layer close to the surface; that is the ratios of transverse co-ordinates and velocities to longitudinal ones are considered to be negligid2 u aZ"u" axp au2 ble ( y << x, o << u , -<< -1. Merk and Prins ( 9 ) . for the caze of heat transfer, show that this applies where Nan > lo'. They obtained the boundary-layer equations which, written in a form applicable to mass transfer, areThis assumes that the viscosity and diffusivity do not vary with concentration, which will be approximately true for the dissolution of sparingly soluble materials. who employs the method of characteristics to solve the time dependent free convection equations of momentum and energy placed in the integral form for heat transfer from a vertical flat plate. The result, written in a form applicable to mass transfer and with the assumption that N s , >> 1, is
E X P E R I M E N T A L METHODIn order to obtain a large variation in Schmidt and Grashof numbers a series of systems was investigated, namely benzoic acid in water, salicylic acid in benzene, succinic acid in n-butanoI, and succinic acid in acetone. Six difFerent sizes of spheres were used for each system, the diameters ranging from v4 to %in. in '/ain. increments. The spheres were made by compression of the crystalline acid between a punch and die in a fly-press, giving pellets of high sphericity and density.The most important factors in the design of the apparatus were that the sphere must be held rigidly in the stagnant fluid at constant temperature, and in order to measure the rate of dissolution, photographs of the dissolving sphere must be free from distortion. A column of square cross section with plane glass windows in two opposite sides was chosen, since this would eliminate optical distortion effects arising out of the difference in refractive index between the solvent in the column and the water in the constant-temperature jacket which would enclose it. In deciding on a column 6-in. square th...