First-principles alloy theory is used to establish the γ-surface of Fe-Cr-Ni alloys as function of chemical composition and temperature. The theoretical stacking fault energy (SFE) versus chemistry and temperature trends agree well with experiments. Combining our results with the recent plasticity theory based on the γ-surface, the stacking fault formation is predicted to be the leading deformation mechanism for alloys with effective stacking fault energy below ∼ 18 mJm −2 . Alloys with SFE above this critical value show both twinning and full slip at room temperature and twinning remains a possible deformation mode even at elevated temperatures, in line with observations. Keywords: Austenitic steels, γ-surface, First-principles theory, Plastic deformation modeThe stacking fault energy (SFE) of austenitic steels is an important physical parameter closely related to the dislocation-mediated plastic behaviors. Especially, in the so-called transformation-induced plasticity (TRIP) and twinninginduced plasticity (TWIP) steels, SFE is recognized as the fundamental parameter that determines the transition of plastic deformation mode from the γ-ǫ/α ′ martensite phase transformation to twinning. Extensive studies have been performed to establish the SFEs in various alloys and the effect of composition, temperature, grain size, strain rate, etc. on the SFE (see Ref.[1] and references therein). It was observed that the deformation-induced martensitic transformation is characteristic for alloys with negative or low SFE. Twinning is the effective deformation mode for intermediate SFE values placed roughly between 18 and 45 mJm −2 . For high SFEs, plasticity and strain hardening are controlled merely by the glide of full dislocation.[2] However, the upper limit for the TRIP mechanism is diverse in various studies. Sato et al. [3] and Allain et al. [4] suggested SFE values of 20 and 18 mJ m −2 , respectively, as the critical values in high-Mn steels separating the TRIP and TWIP mechanisms. Frommeyer et al. [5] reported that SFEs larger than about 25 mJm −2 lead to twinning in a stable γ phase, whereas SFEs smaller than about 16 mJm −2 result in ǫ-martensite formation. The SFE may be connected to the stability of the facecentered cubic (fcc) structure with respect to the hexagonalclosed packed (hcp) structures. Within the thermody- * Corresponding author Email addresses: songlu@utu.fi (Song Lu), sekk@postech.ac.kr (Se Kyun Kwon), levente@kth.se (Levente Vitos) namic approach, the SFE is calculated based on the OlsonCohen model [6], which separates the stacking fault formation energy into contributions from the Gibbs energy difference ∆G hcp−fcc and the interfacial energy σ between the fcc and hcp phases, viz.,where ρ is the molar surface density of the fcc (111) plane. In practice, the interfacial energies are often obtained as the difference between the measured SFE and the thermodynamically calculated ∆G hcp−fcc .[6] In this sense, the resulted interfacial energy includes all the errors between the measured SFE a...