Theoretical design of novel energetic salts derived from bicyclo-HMX

Zhang, Cong; Zhao, Fengqi; Xu, Sheng; Ju, Xue‐Hai

doi:10.1007/s00894-018-3835-0

Cited by 2 publications

(2 citation statements)

References 45 publications

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“…The research mode is usually to design and synthesize neutral compounds or salt compounds with specific structures based on theoretical predictions. [11][12][13] In order to improve the synthesis efficiency of energetic salts, reduce labor costs, and greatly improve the synthesis speed, this study took energetic salts as the synthesis target, and used multi-channel automation technology for high-throughput synthesis, which could improve efficiency and reduce labor costs. Increasing the synthesis speed is of great significance for accelerating the synthesis of new energetic salts.…”

Section: Introductionmentioning

confidence: 99%

Method and apparatus for automatic high-throughput synthesis of energetic salts

Wang

Zhou

et al. 2023

J. Phys.: Conf. Ser.

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Energetic materials can instantly combust and release a large amount of energy in responding external impulses. Due to its energy characteristics, it has a wide range of practical applications: military and civilian. Designing high-energy-density materials with better performance, lower sensitivity, and more environmental friendliness has become a hotspot in the field of energetic materials in recent years. Energetic salts are formed by acid-base or metathesis reactions of different types of anions and cations. Energetic salts are a new class of energetic materials which were developed in recent years. Usually, they have high nitrogen content, high enthalpy of formation, high detonation performance, are relative stable to external stimuli, and have a wide range of application prospects in the fields of new explosives: low characteristic signal propellants, gas generators, low smoke or smokeless pyrotechnics. The synthesis method of energetic salts is simple, and the types of energetic materials are greatly enriched. This research takes energetic salts as the synthesis target and adopts multi-channel automation technology for high-throughput synthesis, which can improve the efficiency, reduce labor costs, and greatly increase the synthesis speed, which is of great significance for accelerating the synthesis of new energetic salts.

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Section: Introductionmentioning

confidence: 99%

Method and apparatus for automatic high-throughput synthesis of energetic salts

Wang

Zhou

et al. 2023

J. Phys.: Conf. Ser.

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“…At present, there are few research reports in this area. Therefore, in this study, combined with the high-throughput synthesis platform developed by the research group, oxidation reactions [11][12][13][14][15] , nitration reactions [16][17][18][19] , as well as ion exchange reactions [20][21][22][23][24][25] were studied. Although there is no technical difficulty in handling the synthesized energetic salts described in this paper, they should be handled with extreme care using the best safety practices (face shield, gloves, 2.1.…”

Section: Introductionmentioning

confidence: 99%

Research on Integrated Parallel Reactions for the High Throughput Preparation Energetic Materials

Wang

Zhou

et al. 2023

J. Phys.: Conf. Ser.

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The high-throughput automatic sample addition platform technology was applied to the large-scale sample addition, pretreatment, and high-throughput synthesis of simple compounds in many fields. With the introduction of material genome technology into the field of high energy energetic materials (HEDMs), the energetic materials genome (EMG) project is implemented. Completing different reaction types at the same time has become key to high-throughput synthesis of energetic materials. In this study, three common synthetic methods (nitration, oxidation and ion exchange reactions) were selected and successfully integrated on the high-throughput automatic sample addition platform. The parallel reactions could be used for preparing energetic materials. The method is viable for high-throughput synthesis of HEDMs. The method improves the efficiency, safety, labor costs compared to conventional methods, which is of great significance for accelerating the synthesis of HEDMs.

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Theoretical design of novel energetic salts derived from bicyclo-HMX

Cited by 2 publications

References 45 publications

Method and apparatus for automatic high-throughput synthesis of energetic salts

Method and apparatus for automatic high-throughput synthesis of energetic salts

Research on Integrated Parallel Reactions for the High Throughput Preparation Energetic Materials

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