“…It is only quite recently that the volume effect based on the symmetry-conforming principle of point defects was proposed and recognized as the intrinsic governing mechanism of ferroelectric aging (Lambeek & Jonker, 1986;Zhang & Ren, 2006;Yuen et al 2007). Compared to tetragonal ferroelectrics, orthorhombic ferroelectrics are as interesting and as important, since orthorhombic ferroelectric phase lies widely in ferroelectrics similar to tetragonal ferroelectric phase (Yamanouchi et al, 1997;Saito et al, 2004;Wang et al, 2006 lead-free piezoelectric applications due to their good piezoelectric properties and high Curie temperatures (Yamanouchi et al, 1997;Saito et al, 2004). However, literature report on the aging effects in this class of (lead-free) ferroelectrics remains essentially insufficient till today (Feng & Or, 2009 so as to provide a relatively complete picture about the aging on both orthorhombic and tetragonal ferroelectrics for the related communities (Feng & Or, 2009).…”