Abstract:The structure of known copper(II) complex with 4-hydroxybenzoic acid hydrazide has been corrected on the basis of a new X-ray analysis. It has been found, that the sulfate(VI) ion is bonded in apical position of Cu(II) coordination pyramid having two organic ligands at the base. Two water molecules are not coordinated as has been postulated before, but stabilizes the sulfate(VI) group orientation and link the layers of complex molecules by strong hydrogen bonds. The detailed interpretation of the measured IR a… Show more
In the current review the content of the journal Structural Chemistry for the calendar year 2010 is related to thermochemistry. To a short summary of each article in this volume of the journal a thermochemical comment is added.
In the current review the content of the journal Structural Chemistry for the calendar year 2010 is related to thermochemistry. To a short summary of each article in this volume of the journal a thermochemical comment is added.
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