The Vibrational Spectra of Cobalt and Iron Cyclidene Dioxygen Complexes and Their Relation to Molecular Geometry

Masarwa, Mohamad; Sauer-Masarwa, Alexandra; Ye, Naidong; Busch, Daryle H.

doi:10.1080/00958979308037117

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Axial Ligands1

Infrared Spectroscopy1

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1994

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(2 citation statements)

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“…and 0-0 distance 1.32(2) A, as expected for a coordinated superoxide. 55 The cavity is unaltered in width on coordination, but the bridge folds away from the ligand, in exactly the same fashion as for the -(CH2)8bis(thiocyanato) complex. The longer polymethylene bridges generally combine partial disorder with high thermal motion for their central atoms.…”

Section: Axial Ligandsmentioning

confidence: 85%

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Iron and Cobalt "Lacunar" Complexes as Dioxygen Carriers

Busch¹,

Alcock²

1994

Chem. Rev.

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192

155

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Section: Axial Ligandsmentioning

confidence: 85%

“…Replacing the R3 = Me group with phenyl caused a shift of the vibrational mode to 1157 cm-1 for both metal cyclidenes, and the frequency shows an even-odd alternating increase as the polymethylene chain length increases. 83 IV. Dloxygen Affinities…”

Section: Infrared Spectroscopymentioning

confidence: 99%