The use of hydrophobic rings for the measurement of interfacial tensions

Krynitsky, John A.; Garrett, William D.

doi:10.1016/0095-8522(63)90083-7

Cited by 9 publications

(5 citation statements)

References 6 publications

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“…First, from eqn. (5), unless (rh)h/v = (rh)h/w and (l-'w)w/v = (r&w the work of adhesion per mole has no meaning. We may, however, reasonably expect these equalities to be at least approximately correct.…”

Section: Methodsmentioning

confidence: 99%

Thermodynamic properties of aliphatic hydrocarbon/water interfaces

Aveyard¹,

Haydon²

1965

Trans. Faraday Soc.

210

102

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alkanes against water have been measured over a range of temperatures, and the results discussed in terms of hydration of the hydrocarbon surfaces. The tension against temperature plots were in all cases linear, in contrast to the results for hexane given by Franks and Ives. The influence of electrolyte in the aqueous phase and of hydrocarbon homologues and isomers in the hydrocarbon phase on this linearity have been investigated. In the present temperature range, non-linearity may occur for some normal alkane mixtures but not others. This phenomenon seems to be related to discontinuities in the density against temperature curves for the hydrocarbons.

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Section: Methodsmentioning

confidence: 99%

Thermodynamic properties of aliphatic hydrocarbon/water interfaces

Aveyard¹,

Haydon²

1965

Trans. Faraday Soc.

210

102

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“…The main difficulty is undoubtedly the problem of the wettability of the ring. Recently, Krynitsky and Garret (73) have suggested the use of hydrophobic rings.…”

Section: Author This Article Was Written Whilementioning

confidence: 99%

Aqueous Interfaces—methods of Study and Structural Properties

Drost-Hansen¹

1965

Ind. Eng. Chem.

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“…Over 50 years, surface chemists have occasionally measured surface tension of some liquids (mostly water) in contact with vapors of immiscible, more volatile liquids at constant temperatures and varying pressures primarily to deduce adsorption isotherms (e.g., ref [6][7][8][9][10][11][12][13][14]. Also found in the literature are interfacial tension values mostly for water-organic liquid combinations (e.g., ref [15][16][17][18][19][20]. Those measurements are limited to specific combinations of substances and, in most cases, to narrow temperature ranges or only to room temperatures.…”

Section: Introductionmentioning

confidence: 99%