The Ternary Systems KClO3—K2SO4—H2O and NaClO3—Na2SO4—H2O1

Ricci, John E.; Yanick, Nicholas S.

doi:10.1021/ja01282a020

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Chlorine Oxygen Acids and Salts, Chloric Acid and Chlorates

Mendiratta

Duncan

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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Sodium chlorate is the primary raw material for the manufacture of chlorine dioxide, a bleaching agent in the pulp and paper industry. Increases in the chlorine dioxide substitution for chlorine in pulp bleaching have resulted in an average growth of 12%/y in production. Sodium chlorate is prepared electrolytically. The modern technology described minimizes sodium chloride and sodium dichromate impurities. Chlorates are powerful oxidizers, and they are also used in perchloric salt and uranium production. Chloric acid technologies have been developed which allow the generation of chlorine dioxide directly from the acid, without the formation of sodium salts in the generator.

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