The luminescence and transient absorption of PbWO 4 crystals were studied. The electron beam (10 us, E 270 keV) was used as excitation source. The kinetics of luminescence is complicated -the prompt rise of luminescence intensity is followed by a slow (r, 100 ns) rise. The luminescence decay at 80 K is nearly exponential with rd 4.0-4.5 μs. The decay kinetics of transient absorption at 3.5 eV can be described roughly by two exponents with time constants r 1 Ń 100 ns and 7-2 4.0 μs. A common process responsible for absorption relaxation and luminescence rise is suggested. The luminescence center excitation occurs during recombination process via Pb2+ excited state formation and subsequent energy transfer to WO4 -group.