This paper deals with the topic of a modern electronic toll collection system that will be applied in the Republic of Croatia from the year 2022 onwards. The paper primarily analyses the existing toll collection systems in Croatia, as well as in the European Union. Modern electronic toll collection systems were analysed with an emphasis on the ANPR (Automatic Number Plate Recognition) system, because ANPR technology will be used in Croatia after the restructuring of road traffic occurs. ANPR is not a new technology, however in the last twenty years it has found its wider application. This happened mostly thanks to local and global infrastructural development and technological improvements therefore in turn infrastructure required for the operation of this system became cheaper. By applying the ETC and ANPR, Croatia will have a system in line with European directives and practices which are being applied in other European countries. The system will in turn significantly raise the quality of road traffic in Croatia and reduce its costs.