The synthesis and characterization of iron colloid catalysts in inverse micelle solutions

Martino, Anthony; Stoker, M. W.; Hicks, Michael; Bartholomew, Calvin H.; Sault, Allen G.; Kawola, J.S.

doi:10.1016/s0926-860x(97)00074-4

Cited by 51 publications

(26 citation statements)

References 79 publications

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“…The reducing agent, whether it is strong or mild toward a specific reaction, must also be carefully chosen as it governs the rate of the nucleation and growth processes (65)(66)(67). The synthesis of metallic nanoparticles can be carried out in solution or in a water-in-oil emulsion (68)(69)(70)(71). The selection of the method is based on the precursors used as well as the nature of the desired nanoscale particles.…”

Section: Synthesis Of Metallic Nanoparticlesmentioning

confidence: 99%

Synthesis of Nanoparticles for Biomass Conversion Processes

Wabeke

Al-Zubaidi

Adams

et al. 2014

ACS Symposium Series

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The design and synthesis of well-defined metallic and bimetallic nanoparticles (NPs), their characterization, and the assessment of how their size and shape-dependent properties influence their applications are important areas of investigation for advancing green technologies that protect the environment. This chapter reviews recent advances in the design and synthesis of metallic, bimetallic and semiconductor nanoparticles and their emerging applications in the production of energy and chemicals from biorenewable materials. This contribution focuses on nanoparticle-mediated processes for biomass transformation that include hydrogenation, hydrogenolysis, decarboxylation, small molecule oxidation, conversion of cellulosic materials, hydrocarbon formation, and production of fuel cells. These processes all have significant potential for development of green technologies.

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Section: Synthesis Of Metallic Nanoparticlesmentioning

confidence: 99%

Synthesis of Nanoparticles for Biomass Conversion Processes

Wabeke

Al-Zubaidi

Adams

et al. 2014

ACS Symposium Series

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show abstract

“…According to this classifi cation, there are two major methods for synthesis of metallic nanoparticles (especially for synthesis of zero-valent iron nanoparticles: solution synthesis or a water-in-oil emulsion synthesis [19,82,83] . Solution synthesis involves the synthesis of metal nanoparticles by chemical reduction of the metal salt in solution [84] .…”

Section: Synthesis Of Metallic Nanoparticlesmentioning

confidence: 99%

Nanoscale materials for organohalide degradation via reduction pathways

Bolandi

Nick

Obare

2012

Nanotechnology Reviews

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The unique chemical and physical properties of nanoscale materials have led to important roles in several scientifi c and technological fi elds. Environmental chemistry processes have benefi ted from the enhanced reactivity of nanoscale particles relative to their bulk counterparts with contaminants. Here, we describe recent advances in the synthesis and characterization of metallic and bimetallic nanoparticles that have been effective toward degrading toxic organohalide contaminants. We then review the degradation mechanisms involved in the reactions of nanoscale particles with organohalides via reduction pathways. We also discuss an emerging area -the degradation of organohalides via multi-electron transfer pathways.

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“…Alternative precursors, such as iron-oleate and iron(II) bis(trimethylsilyl)amide (Fe[NSi(Me 3 ) 2 ] 2 ), were also introduced to Fe nanoparticle synthesis [42,108]. There has also been reports of Fe nanoparticles via reduction of Fe(acac) 3 and other iron salts [109][110][111][112][113][114][115]. Although the particle size is well-controlled, the syntheses do reveal that the Fe particles so prepared are extremely reactive and subject to facile oxidation, giving various iron oxide nanoparticles.…”

Section: Synthesis and Stabilization Of Metallic Fe Co And Feco Parmentioning

confidence: 99%

Chemical Synthesis, Self-Assembly and Applications of Magnetic Nanoparticles

Peng

Kim

Sun

2009

Annual Review of Nano Research

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This chapter reviews recent advances in chemical synthesis, selfassembly, and applications of novel magnetic nanomaterials in the past few years. The chemical syntheses of several important classes of magnetic nanoparticles are covered, including ferrites, metallic iron, cobalt, alloys, and rare-earth hard magnets. Several examples of shapecontrolled synthesis of nanoparticles and shape-induced texture in selfassembled nanoparticle superlattices are also outlined. Potential applications, particularly in data storage, permanent magnet and biomedicine, of these nanoparticles and assemblies are discussed.

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The synthesis and characterization of iron colloid catalysts in inverse micelle solutions

Cited by 51 publications

References 79 publications

Synthesis of Nanoparticles for Biomass Conversion Processes

Synthesis of Nanoparticles for Biomass Conversion Processes

Nanoscale materials for organohalide degradation via reduction pathways

Chemical Synthesis, Self-Assembly and Applications of Magnetic Nanoparticles

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