The stereochemistry of the 1,4-addition of dibromocarbene to 1,2-dimethylenecycloheptane

Neuartig in dreierlei Hinsicht ist die Reaktion des [5]Metacyclophans 1 mit dem (intermediären) Phenylphosphiniden‐Komplex 2. Sie verläuft unter Bildung des 7‐Phosphanorbornadiens 3 und ist die erste 1,4‐Addition eines Phosphiniden‐Komplexes an ein ungesättigtes System, die erste Addition eines Phosphiniden‐Komplexes an einen Benzolring und die erste [4+1]‐Cycloaddition an ein Aren.

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1,4-Addition eines terminalen Phosphiniden-Komplexes an [5]Metacyclophan

Eis

Komen

Kanter

et al. 1998

Angewandte Chemie

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ChemInform Abstract: The Stereochemistry of the 1,4‐Addition of Dibromocarbene to 1,2‐Dimethylenecycloheptane.

1990

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Binding constant and transport property of S-Naproxen molecularly imprinted composite membrane

Wang

et al. 2009

Journal of Membrane Science

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The stereochemistry of the 1,4-addition of dibromocarbene to 1,2-dimethylenecycloheptane

Cited by 15 publications

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1,4-Addition eines terminalen Phosphiniden-Komplexes an [5]Metacyclophan

1,4-Addition eines terminalen Phosphiniden-Komplexes an [5]Metacyclophan

ChemInform Abstract: The Stereochemistry of the 1,4‐Addition of Dibromocarbene to 1,2‐Dimethylenecycloheptane.

Binding constant and transport property of S-Naproxen molecularly imprinted composite membrane

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