The article presents the results of studies to determine the dependence of the degree of adhesion and the separation force of the powder coatings layer on the roughness parameter of the substrate, as well as the contact angle of wetting for various methods of preparing the painted surface by chemical methods. In addition, practical tests for stain resistance were carried out, which showed the absence of corrosion damage, as well as a slight change in color, gloss of coatings, chalking and dirt retention on the studied coating samples.Knowledge of the surface tension coefficient and the work of adhesion allows us to obtain information about the energy state of individual near-surface molecules, which is especially important to consider when developing new methods for diagnosing interphase boundaries, as well as methods for studying the interaction of molecules at these boundaries [1,9].One of these methods can be based on measurements of the contact angle of wetting, which can be carried out either directly or using capillary phenomena [13].Based on the equilibrium condition of interface (G) of three phases, one of which is gas (Figure 1) [15], it is easy to show that the surface tension coefficient σ12 is related to the contact angle θ by the following expression [14]: