“…Alkaline flooding has been found to be an efficient and economical enhanced oil recovery (EOR) technique for decades. − In recent years, alkalis have also been integrated with other EOR techniques such as steam-assisted gravity drainage (SAGD), − surfactant and/or polymer flooding, − and nanoparticle-assisted processes − by taking the advantages of reducing the surfactant adsorption loss, protecting surfactant against divalent ions, and reacting with the petroleum acids to form in situ surfactant . The in situ generated surfactant helps to reduce the interfacial tension (IFT) between oil and the aqueous phase, while amphiphilic components (e.g., resins, asphaltenes, and natural petroleum acids) in crude oil strengthen the stability of a water–oil emulsion. , The lower the IFT is, the more easily the crude oil could be emulsified with water. , Once an O/W emulsion is formed, the mobility of the oil phase can be greatly improved . The formation of a W/O emulsion increases the viscosity of the displacing fluid, leading to an improved mobility ratio, , reducing water channeling, damping viscous fingering behavior, and then enhancing oil recovery. , However, the dispersed water droplets in W/O emulsions make the refinement of the crude oil a difficult and expensive task.…”