A series of TiB 2 -TiC-Ni composites were prepared to develop materials with enhanced mechanical properties for structural application. Submicron TiB 2 -TiC powders were synthesized using a patented carbon coated precursor method. The composites had about 99% relative density after sintering at a temperature of 1550°C in flowing argon. TiB 2 -TiC-Ni composites showed superior sintering and mechanical properties comparing with monolithic TiB 2 and TiC counterparts because of the enhanced microstructures. Phases, grain morphologies, pores sizes, sintering behaviors, and mechanical properties were correlated with the ratio of TiB 2 /TiC and Ni content. The plate like TiB 2 grains were observed in the composites. Toughening mechanism was determined as metallic binder plastics deformation, bridging, and debonding of the TiB 2 /TiC interface. TiB 2 -TiC-Ni composites have good combinations of hardness and fracture toughness as 24.23 GPa, 7.41 • / , and 21.85 GPa, 8.44 • / , with Ni content of 5 and 10 wt%, respectively.WC-Co cermet, due to its superior finishing properties, hardness, and wear resistance [5][6][7]. Similarly, titanium carbide (TiC) based cermet, TiC-TiN-(Ni, Mo, Co), is also an ideal candidate for cutting tool materials owing to its excellent wear resistance and high hardness [8][9][10][11][12]. Except cutting tool materials, both TiB 2 and TiC also have various other crucial applications from structural to electronic fields such as impact resistant armor, wear resistance components, corrosion resistance coatings, and electrode materials [1,2,13,14]. Comparing with monolithic TiB 2 or TiC cermets, several reports indicate that TiB 2 -Ti(C,N)-(Ni,Mo) composite has outstanding properties including hardness, fracture toughness, and strength [5][6][7]15]. However, in that respect is no research study the influence of