The reaction of methyl vinyl ketone with alpha‐ and beta‐eleostearic acids

Placek, Lida L.; Bickford, W. G.

doi:10.1007/bf02639642

Cited by 5 publications

(3 citation statements)

References 11 publications

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“…For reaction between methyl vinyl ketone and the eleostearic acids, heating at 150°C. was continued for 16 hours (42). Although conjugated octadecadienoic acids would react with maleic anhydride on refluxing in heptane for 4 hours, a temperature of 206°C.…”

Section: Rates In Reactions Bymentioning

confidence: 99%

Some New Ideas on Oxidation

Mayo¹

1960

Ind. Eng. Chem.

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Section: Rates In Reactions Bymentioning

confidence: 99%

Some New Ideas on Oxidation

Mayo¹

1960

Ind. Eng. Chem.

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“…Methyl Vinyl Ketone-Methyl alpha-Eleostearate Adduet. Preparation of this adduct and its properties have been described in the preceding article (5).…”

Section: Methodsmentioning

confidence: 99%

“…I N PURSUING further the possibility of producing from tung oil new and improved plasticizers (1,2,3,4) for the vinyl chloride copolymers, it appeared of interest to evaluate the methyl vinyl ketone-methyl alpha-eleostearate adduct and certain of its derivatives as plasticizers. As shown in the preceding article (5), the methyl vinyl ketone-methyl alpha-eleostearate adduet is a ring compound containing keto and ester groups as well as cyclic and exocyclic ethylenic bonds. It might be expected that this compound would have exceptional plasticizing efficiency owing to the presence of a keto group in addition to an ester group.…”

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confidence: 87%

Plasticizer properties of methyl vinyl ketone‐methylalpha‐eleostearate adduct and derivatives

Placek

Magne

Bickford

1959

J Americ Oil Chem Soc

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Summary The Diels‐Alder adduct of methyl vinyl ketone and methylalpha‐eleostearate was subjected to modification by hydrogenation and epoxidation of its unsaturated centers and by aromatization of its cyclohexene nucleus. These derivatives, as well as the original adduct, were intercompared with DOP as primary plasticizers for vinyl chloride‐vinyl acetate copolymer. All of these materials were found to be highly compatible as primary plasticizers and generally more efficient than DOP. The stocks plasticized with the hydrogenated and epoxidized adducts exhibited very good thermal stability on long exposures to heat. The epoxidized adduct not only imparted excellent heat stability to the plastic but also prevented deterioration on exposure to ultraviolet irradiation.

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Diels‐Alder‐Reaktionen auf dem Fettgebiet

Kaufmann

Gruber

Brüning

1961

Fette, Seifen, Anstrichm.

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AUS den2 Deiitshcn Instiftit fiir Fettforsclzzing, Miinster (West!.) Herstellung d1.r Diels-Alder-Addukte van Sorbinsaure-methylester mit p-Benzochinon, l,4-Naphthochinon und Acrolein, von P-Elaeostearinsaure-methylester mit .4crylsaure, Crotonaldehyd, Crotonsbure-athyl'ester und Acetylendicarbonsaure-dimethylester und van P-Licansaure-methylester mit Acrolein, Acrylsaure, Crotonaldehyd, Crotons&ure-dtliylester und Methylvinylketon in reinem Zustand. Reactions Diels-Alder dans le domaine des lipidesPreparation A 1'Ctat piir des produits d'addition Diels-Alder du sorbdte de mcthyle avec la p-benzoquinone, la 1,4-naphtoquinone et l'acroleine, du betaelaeostearate de methyle avec I'acide acrylique, le crotonaldehyde, le crotonate d'elhyle et l'ester dim4thyIacetylenedicarboxylique et du beta-licanate de methyle avec I'acroleine, I'acide acrylique, le crotonaldehyde. le crotonate d'cthyle et la methylvinylcetone. Diels-Alder-Reaction in the Fat-Field

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The reaction of methyl vinyl ketone with alpha‐ and beta‐eleostearic acids

Abstract: Summary Methyl vinyl ketone was found to be an active dienophile for the modification of the eleostearate

Cited by 5 publications

References 11 publications

Some New Ideas on Oxidation

Some New Ideas on Oxidation

Plasticizer properties of methyl vinyl ketone‐methylalpha‐eleostearate adduct and derivatives

Diels‐Alder‐Reaktionen auf dem Fettgebiet

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