2009
DOI: 10.1002/adma.200801098
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The Origin of the Magnetism of Etched Silicon

Abstract: A recent report of ferromagnetism appearing in silicon after etching in hot KOH (Kopnov et al., Adv. Mater. 2007, 19, 925) is shown to be due to iron from the pyrex glassware, which precipitates on the silicon surface in the form of well‐separated ferromagnetic nanoparticles. The reaction is explained in terms of the Pourbaix diagram.

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Cited by 52 publications
(30 citation statements)
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“…Similar behaviour is found in other iron particles. For instance, carbonyl iron with a 6 -8 μm particle size follows the same law, with c = 2.1, provided the particles are well-separated by dispersing them in icing sugar to minimize dipole-dipole interactions [17]. Iron particles smaller than 200 nm dispersed in graphite behave similarly.…”
Section: Resultsmentioning
confidence: 69%
See 1 more Smart Citation
“…Similar behaviour is found in other iron particles. For instance, carbonyl iron with a 6 -8 μm particle size follows the same law, with c = 2.1, provided the particles are well-separated by dispersing them in icing sugar to minimize dipole-dipole interactions [17]. Iron particles smaller than 200 nm dispersed in graphite behave similarly.…”
Section: Resultsmentioning
confidence: 69%
“…Arrays of well-separated quasi-spherical iron particles on silicon were produced by a method involving etching silicon in hot KOH, described in [17]. The average particle diameter is of order 200 nm, and the average spacing is about 3 μm.…”
Section: Methodsmentioning
confidence: 99%
“…The common method of characterization of gold nanoparticles is superconducting quantum interference device (SQUID) magnetometry, which while very sensitive, is a nonspecific tool which cannot discriminate against parasitic secondary magnetic phases and measurement artifacts. It is thus easy to misinterpret the origin of magnetism in a given sample [72][73][74][75]. Of particular concern are impurities of iron and its oxides, which form magnetic materials.…”
Section: Experimental Studiesmentioning
confidence: 99%
“…This issue has become of a great importance when many laboratories started to investigate materials deposited on substrates made from some of hardest substances like sapphire or SiC which are very likely to abrade the softer material of the tools they are handled by. But even Si requires a great deal of care because of its strong tendency to bind iron or nickel [12,43], or to absorb on its surface submicron Fe-rich particles during etching from even a high grade KOH [44]. Here we consider the case of a sapphire substrate and in Fig.…”
Section: Artifacts Due To Improper Sample Handlingmentioning
confidence: 99%