1984
DOI: 10.1016/s0020-1693(00)83584-7
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The nature of the blue isomer of Ni(1,2-diaminoethane)2(NO2)2

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Cited by 11 publications
(2 citation statements)
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“…In particular, one of the NO 2 - ions leaves the coordination sphere, while the other chelates the Ni II center with the two oxygen atoms. A similar structural rearrangement had been proposed for the Ni II (ethylenediamine) 2 (NO 2 ) 2 complex ), supporting the mechanism of the simultaneous rotation of the two NO 2 - ions.…”
supporting
confidence: 76%
“…In particular, one of the NO 2 - ions leaves the coordination sphere, while the other chelates the Ni II center with the two oxygen atoms. A similar structural rearrangement had been proposed for the Ni II (ethylenediamine) 2 (NO 2 ) 2 complex ), supporting the mechanism of the simultaneous rotation of the two NO 2 - ions.…”
supporting
confidence: 76%
“…The reversible change from the low-temperature red form to the hightemperature blue form of Nienz(NOz) 2 occurs at 383-423 K. According to Hitchman [3], the blue isomer contains one chelating and one ionic nitrite per metal. Microscopic observations showed that a very distinct reaction front moves across the crystal, parallel to the crystal edges [4] (Fig.…”
Section: Linkage Isomerization In Nien2(no2)mentioning
confidence: 99%